{"id":"W4236407105","doi":"10.1139/cjc-79-5-6-1040","title":"Synthesis of sulfated mono- and ditertiary phosphines, complex chemistry and catalysis","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Sulfation; Organic chemistry; Combinatorial chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001687674,0.000315142,0.0002721933,0.0002474468,0.0002295575,0.0003014918,0.0004542748,0.0003355684,0.002526089],"category_scores_gemma":[0.0002032356,0.0001797697,0.0001515778,0.0003127169,0.0001684959,0.000409004,0.0002939476,0.0004705548,0.0006807515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003780696,"about_ca_system_score_gemma":0.0003657997,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005517264,"about_ca_topic_score_gemma":0.001099111,"domain_scores_codex":[0.9999223,0.00001043358,0.000009263651,0.00001815919,0.00002019331,0.00001970688],"domain_scores_gemma":[0.9999516,0.000007555588,0.000009502351,0.00001036395,0.000008910455,0.00001200104],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004400471,0.000113679,0.0002046473,0.0007130905,0.000042492,0.000520761,0.0002980373,0.002269454,0.9514415,0.008537347,0.001429232,0.03398968],"study_design_scores_gemma":[0.00003447379,0.0003790808,0.0002916575,0.000009647666,0.00001658971,0.0003041174,0.00002434971,0.001202713,0.9830322,0.0005272599,0.01416607,0.00001182044],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9324325,0.006343046,0.02672642,0.0004321265,0.0001863594,0.0002242149,0.001162365,0.000412325,0.03208064],"genre_scores_gemma":[0.9756038,0.002762539,0.009695692,0.00007155989,0.00002291785,0.00006079739,0.0005812556,0.00004293837,0.01115853],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002526089,"threshold_uncertainty_score":0.008450568,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007899641935301481,"score_gpt":0.1853418308296998,"score_spread":0.1774421888943983,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}