{"id":"W4236441744","doi":"10.1002/1521-3757(20010601)113:11<2187::aid-ange2187>3.0.co;2-e","title":"Titanocene-Catalyzed Coupling of Amides in the Presence of Organosilanes To Form Vicinal Diamines","year":2001,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Vicinal; Catalysis; Chemistry; Diamine; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000142627,0.0001772647,0.0002993855,0.00003350584,0.00003088449,0.000008712199,0.0005092146,0.00009771447,0.0004165634],"category_scores_gemma":[0.000448436,0.0001393099,0.00006177546,0.0003337859,0.0001148244,0.00007157777,0.0001001447,0.0001322267,0.000005178214],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004813724,"about_ca_system_score_gemma":0.00004302883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005687616,"about_ca_topic_score_gemma":0.00004660519,"domain_scores_codex":[0.9987981,0.00000228194,0.0003895334,0.0002534374,0.0002941113,0.0002625641],"domain_scores_gemma":[0.9988249,0.0003364797,0.0001603151,0.0005361015,0.00008730994,0.00005489518],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005524155,0.00007846829,0.01194153,0.0002324582,0.00001371807,0.00001802472,0.0008133635,0.00002454417,0.9865311,0.00001160957,0.0001076157,0.0001723205],"study_design_scores_gemma":[0.0003558003,0.000009041095,0.0004591234,0.0001930106,0.00002217554,0.0000455477,0.001230006,0.00001294906,0.9968373,0.0001866268,0.000500284,0.0001481255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938253,0.0003873652,0.00003895427,0.0002097273,0.00002329522,0.00007631209,0.00002648454,0.000024938,0.00538769],"genre_scores_gemma":[0.9990323,0.0001201953,0.000267315,0.00002610414,0.00009559099,0.00001693539,0.00001837183,0.00002355607,0.0003996877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01148241,"threshold_uncertainty_score":0.5680892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01577814941498976,"score_gpt":0.2540137740250299,"score_spread":0.2382356246100402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}