{"id":"W4237097111","doi":"10.26434/chemrxiv.7323989","title":"N-Heterocyclic carbene-functionalized magic number gold nanoclusters","year":2018,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Nanoclusters; Carbene; Metal; Cluster (spacecraft); Ligand (biochemistry); Chemistry; Gold cluster; Nanotechnology; Crystallography; Catalysis; Materials science; Computational chemistry; Organic chemistry; Electronic structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005621884,0.0001790988,0.0001526814,0.0001204845,0.0001120642,0.000184593,0.0002649086,0.0002756983,0.001423768],"category_scores_gemma":[0.0001594974,0.00007748127,0.00008033567,0.0000844408,0.0001788289,0.0001986477,0.0001928359,0.0001903236,0.0003595621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000431151,"about_ca_system_score_gemma":0.0001522123,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001115864,"about_ca_topic_score_gemma":0.002250572,"domain_scores_codex":[0.9999038,0.000006192845,0.000005078951,0.00003657026,0.00003257947,0.00001573068],"domain_scores_gemma":[0.9999439,0.00001092663,0.00001178057,0.00001022745,0.000009876207,0.00001335081],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004302876,0.000008097094,0.00006442549,0.00002493229,0.000003273245,0.00003088617,0.000009191929,0.0002156162,0.997039,0.0004306462,0.0001716408,0.001959338],"study_design_scores_gemma":[0.000008248448,0.00004977165,0.0003017294,0.000001579292,0.00000239068,0.00003223813,0.000003917178,0.0008689433,0.9970185,0.00004836698,0.001661122,0.000003338082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842426,0.0009311996,0.005014031,0.0001318163,0.00006636841,0.00003744983,0.0002748828,0.0002523845,0.00904922],"genre_scores_gemma":[0.9924387,0.0002325241,0.004213944,0.00006392003,0.000008573041,0.00001992148,0.0001588349,0.00002508371,0.002838567],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001423768,"threshold_uncertainty_score":0.004763007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02539460706292882,"score_gpt":0.2716953010433626,"score_spread":0.2463006939804338,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}