{"id":"W4237332769","doi":"10.1002/ange.201409969","title":"Frustrated Lewis Pair Activation of an <i>N</i>‐Sulfinylamine: A Source of Sulfur Monoxide","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Frustrated Lewis pair; Intramolecular force; Chemistry; Borane; Sulfur; Carbene; Carbon monoxide; Monoxide; Lewis acids and bases; Medicinal chemistry; Catalysis; Photochemistry; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001524583,0.0002609495,0.0004064805,0.0000430432,0.00004233368,0.0000157351,0.0003387472,0.0003100526,0.001067139],"category_scores_gemma":[0.0002069713,0.0002667999,0.0001199904,0.000219703,0.000133789,0.0001652496,0.00006349107,0.0002176572,0.000007850343],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004705272,"about_ca_system_score_gemma":0.00007223713,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001918682,"about_ca_topic_score_gemma":0.000009741756,"domain_scores_codex":[0.998557,0.00001615189,0.0004836362,0.00037224,0.0002880428,0.0002829311],"domain_scores_gemma":[0.9985656,0.000112232,0.0003491512,0.0006589817,0.0001599835,0.0001540406],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005724981,0.0002022399,0.003942505,0.0003609362,0.00004264453,9.873841e-7,0.0002363557,0.000009289244,0.9928191,0.00001523152,0.0006897949,0.00162366],"study_design_scores_gemma":[0.000954586,0.00004102824,0.0004896062,0.00008846162,0.00004181253,0.000005864254,0.0003137315,0.00004744284,0.9947815,0.00006471155,0.002908003,0.0002632419],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906689,0.00005764053,0.00007363094,0.0001146854,0.00002527499,0.00004510688,0.00002915389,0.0001296687,0.008855955],"genre_scores_gemma":[0.9980875,0.0000146388,0.0002697218,0.00008628533,0.0001956359,0.000008283147,0.0001613443,0.0000528404,0.001123798],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007732157,"threshold_uncertainty_score":0.9999784,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01117174615239487,"score_gpt":0.222333931660838,"score_spread":0.2111621855084431,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}