{"id":"W4237492746","doi":"10.5539/ijc.v9n4p87","title":"Selective Synthesis of Ortho-Substituted 2-Aryl-3-phenyl-1,3-thiazolidin-4-one Sulfoxides and Sulfones by S-Oxidation with Oxone®","year":2017,"lang":"en","type":"article","venue":"International Journal of Chemistry","topic":"Synthesis and Reactivity of Sulfur-Containing Compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Temple University","keywords":"Chemistry; Sulfoxide; Substituent; Sulfone; Aryl; Ring (chemistry); Medicinal chemistry; Selectivity; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003038373,0.000218047,0.0004425594,0.00006250791,0.0001577069,0.0001754532,0.000687336,0.0001643596,0.0001520766],"category_scores_gemma":[0.0006674667,0.0001889466,0.0001277778,0.000032388,0.0003309562,0.000525925,0.00009060277,0.0003019972,0.000001022339],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001110477,"about_ca_system_score_gemma":0.0001638398,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008768088,"about_ca_topic_score_gemma":0.000006896531,"domain_scores_codex":[0.9983704,0.0000109234,0.000518848,0.0002311279,0.0006944497,0.0001742672],"domain_scores_gemma":[0.996845,0.000387791,0.001587276,0.0002816215,0.0007811791,0.0001171149],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005832115,0.000244223,0.02149762,0.00008334299,0.0009190976,0.00003463776,0.0001145132,0.000003741271,0.9693907,0.00003009128,0.0001178468,0.00698099],"study_design_scores_gemma":[0.0009099453,0.0000211051,0.01076091,0.0007015687,0.0001238425,0.000336051,0.000237552,0.00002662047,0.9858695,0.0002130343,0.0005923473,0.0002075616],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899305,0.0002580209,0.0001553246,0.0009071653,0.00008478222,0.00002572666,0.00003723484,0.00001539321,0.008585915],"genre_scores_gemma":[0.9983503,0.0002719027,0.0007758465,0.00001259862,0.0003108034,0.000004640071,0.00001121683,0.00002461299,0.0002380791],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01647877,"threshold_uncertainty_score":0.7705017,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01157345358207674,"score_gpt":0.2407152806130138,"score_spread":0.2291418270309371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}