{"id":"W4237605368","doi":"10.1002/ange.201704991","title":"Addition of a Cyclophosphine to Nitriles: An Inorganic Click Reaction Featuring Protio, Organo, and Main‐Group Catalysis","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research","keywords":"Heterolysis; Cycloaddition; Chemistry; Lone pair; Catalysis; Yield (engineering); Combinatorial chemistry; Organic chemistry; Molecule; Materials science","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002324691,0.0004784738,0.0001443108,0.0001873855,0.0001472017,0.0003158404,0.0002976473,0.0003155067,0.001362261],"category_scores_gemma":[0.0001218622,0.0002151184,0.0002051837,0.0001065384,0.0002961194,0.0004213564,0.000434128,0.0003470888,0.0003881843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003016873,"about_ca_system_score_gemma":0.0002067201,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002992569,"about_ca_topic_score_gemma":0.0005398289,"domain_scores_codex":[0.9998863,0.00001279034,0.000008787612,0.0000304653,0.00003095819,0.00003069531],"domain_scores_gemma":[0.9999577,0.000008620406,0.0000109659,0.000006579484,0.00000437148,0.00001170601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001203741,0.00004933629,0.000138126,0.00007662831,0.00001114132,0.0003172235,0.00004010584,0.000316948,0.9919894,0.001987934,0.0002145164,0.004738317],"study_design_scores_gemma":[0.00002809223,0.000219197,0.0004375626,0.000004039331,0.00001137969,0.0004050275,0.000006758326,0.001019561,0.9944805,0.0001221697,0.003256929,0.000008768489],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9599192,0.0007565527,0.01952978,0.0002358291,0.0001047815,0.0001070113,0.0002659709,0.0003872822,0.01869363],"genre_scores_gemma":[0.9916697,0.0004053765,0.004042831,0.00003384843,0.00001417455,0.00002739125,0.0001254548,0.00002339192,0.00365783],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001362261,"threshold_uncertainty_score":0.004557252,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01552154820490999,"score_gpt":0.259937569629493,"score_spread":0.244416021424583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}