{"id":"W4237933906","doi":"10.1002/ange.201506751","title":"Formal Direct Cross‐Coupling of Phenols with Amines","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Amination; Aryl; Phenols; Halide; Chemistry; Palladium; Coupling reaction; Organic chemistry; Catalysis; Combinatorial chemistry; Primary (astronomy)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003825296,0.000921255,0.0002716626,0.0003027886,0.000205097,0.0001992589,0.0004749765,0.0003311031,0.004423963],"category_scores_gemma":[0.0003348709,0.000222699,0.0003053006,0.0002205433,0.0003055397,0.0003367922,0.0008025431,0.00090254,0.001566899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003871232,"about_ca_system_score_gemma":0.0003666409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006689287,"about_ca_topic_score_gemma":0.001181672,"domain_scores_codex":[0.9996165,0.00005048745,0.00003053243,0.00007481241,0.00009169933,0.0001358562],"domain_scores_gemma":[0.9998155,0.00002988556,0.00003691662,0.00003252981,0.00004425329,0.00004097743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008861423,0.00006766013,0.0001107242,0.0005472868,0.0000544084,0.000515176,0.0001449234,0.0004939414,0.9854046,0.002466368,0.0007777654,0.009328634],"study_design_scores_gemma":[0.00002360162,0.000326295,0.0003805539,0.00001667612,0.00002480342,0.0003293692,0.00001422447,0.0004614574,0.9870183,0.0002189415,0.01117122,0.00001444406],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8572633,0.00874122,0.08386511,0.000550837,0.0008212042,0.0003739843,0.001062881,0.001171886,0.04614961],"genre_scores_gemma":[0.9783558,0.003271995,0.01032047,0.0001492099,0.00005450221,0.0000834562,0.0004842974,0.00008668668,0.007193703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004423963,"threshold_uncertainty_score":0.01479965,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02991856937833865,"score_gpt":0.2822289308849695,"score_spread":0.2523103615066308,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}