{"id":"W4237933906","doi":"10.1002/ange.201506751","title":"Formal Direct Cross‐Coupling of Phenols with Amines","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Amination; Aryl; Phenols; Halide; Chemistry; Palladium; Coupling reaction; Organic chemistry; Catalysis; Combinatorial chemistry; Primary (astronomy)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001320388,0.0001926992,0.0002720839,0.00003783955,0.00008071928,0.00006517754,0.0002028757,0.0001124036,0.000157101],"category_scores_gemma":[0.0001533997,0.0001664919,0.00008421348,0.0001743509,0.0002117685,0.0002708125,0.00008584804,0.0001489869,0.0000229398],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001013625,"about_ca_system_score_gemma":0.00009772683,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001695811,"about_ca_topic_score_gemma":0.00003979142,"domain_scores_codex":[0.9988226,1.052866e-7,0.000268709,0.000270365,0.0003010362,0.000337144],"domain_scores_gemma":[0.9988715,0.00008521826,0.0001639816,0.0004748199,0.0002544482,0.0001500307],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001239746,0.00009318789,0.01613518,0.0001348112,0.00007331195,0.00001106685,0.0004460023,0.0004064497,0.9818689,0.00001758321,0.0005792035,0.0001103812],"study_design_scores_gemma":[0.001042779,0.00002230814,0.0002506452,0.00008218993,0.00005737794,0.00003538499,0.0003365092,0.000141996,0.9951954,0.00003509891,0.002587768,0.0002125548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9729822,0.0002826163,0.0000189523,0.00002813853,0.00007290468,0.00004835112,0.00005581518,0.0001430525,0.026368],"genre_scores_gemma":[0.9957103,0.00001015678,0.00008836532,0.00001132799,0.0002602379,0.0000221332,0.0000937997,0.00004118236,0.003762554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02272807,"threshold_uncertainty_score":0.6789344,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02991856937833865,"score_gpt":0.2822289308849695,"score_spread":0.2523103615066308,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}