{"id":"W4238061180","doi":"10.1002/ange.202006586","title":"Palladium‐Catalyzed Cross‐Coupling of Alkenyl Carboxylates","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrophile; Chemistry; Catalysis; Alkene; Palladium; Carboxylate; Combinatorial chemistry; Catalytic cycle; Oxidative coupling of methane; Base (topology); Coupling reaction; Coupling (piping); Stereochemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008997715,0.0002560786,0.0003830391,0.00003226399,0.0001078427,0.00007909632,0.0003607141,0.0001931048,0.00104844],"category_scores_gemma":[0.000340664,0.000270634,0.0002268948,0.0002619294,0.000216133,0.0001339571,0.0001507712,0.0002958698,0.00008043443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007928159,"about_ca_system_score_gemma":0.00009811528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001734801,"about_ca_topic_score_gemma":0.00001160537,"domain_scores_codex":[0.9984306,1.700002e-7,0.0004566583,0.0004609076,0.0002903193,0.0003613488],"domain_scores_gemma":[0.9987477,0.0001511608,0.0002131632,0.0005060841,0.0001510842,0.0002307802],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005568618,0.00004820434,0.007089732,0.0002767874,0.00009504412,0.00001353556,0.000550741,0.0001848671,0.9911558,0.00002447645,0.0004605465,0.00004455065],"study_design_scores_gemma":[0.0008000613,0.000008205499,0.0003337413,0.00005669085,0.00007818195,0.000009986101,0.0001785864,0.0007158111,0.9953696,0.00004672752,0.002128767,0.0002736413],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944522,0.000618459,0.000009119685,0.0002905993,0.00008629683,0.00006125953,0.0001196929,0.0002343535,0.004128012],"genre_scores_gemma":[0.9986077,0.00005985904,0.00003843418,0.00007518167,0.0004213738,0.00001571562,0.000224069,0.00006018016,0.0004974877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006755991,"threshold_uncertainty_score":0.9999746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02563139726418565,"score_gpt":0.2731570335620091,"score_spread":0.2475256362978235,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}