{"id":"W4238061180","doi":"10.1002/ange.202006586","title":"Palladium‐Catalyzed Cross‐Coupling of Alkenyl Carboxylates","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrophile; Chemistry; Catalysis; Alkene; Palladium; Carboxylate; Combinatorial chemistry; Catalytic cycle; Oxidative coupling of methane; Base (topology); Coupling reaction; Coupling (piping); Stereochemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002783317,0.0006574419,0.0002109488,0.0003521129,0.0001947012,0.0002465559,0.0003893146,0.0003937976,0.002176445],"category_scores_gemma":[0.0002398769,0.0001973842,0.0002191197,0.0002520163,0.0001855793,0.0004034485,0.0004941716,0.000518039,0.0008402502],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002953823,"about_ca_system_score_gemma":0.0003082234,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000504378,"about_ca_topic_score_gemma":0.0008631307,"domain_scores_codex":[0.9997947,0.00002028436,0.0000189972,0.00004808732,0.00004882554,0.00006917624],"domain_scores_gemma":[0.9999197,0.00001086442,0.00001437408,0.0000102882,0.00002033082,0.00002437184],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007488977,0.000042391,0.00009039688,0.0001674014,0.00002383298,0.0002038526,0.00005764719,0.0005266916,0.9905487,0.001611758,0.0002432895,0.006409249],"study_design_scores_gemma":[0.000008656708,0.0000736308,0.0001791387,0.000003868736,0.000009107459,0.0001076946,0.000006690904,0.0003585422,0.9960282,0.00008171519,0.003137794,0.000004926482],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9312201,0.003862511,0.03454014,0.0002611974,0.0002109842,0.0001494724,0.0004441191,0.0004091471,0.02890239],"genre_scores_gemma":[0.9834415,0.002423681,0.005374215,0.00009098859,0.00002080337,0.00003899493,0.0002630375,0.00005368604,0.008293163],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002176445,"threshold_uncertainty_score":0.007280886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02563139726418565,"score_gpt":0.2731570335620091,"score_spread":0.2475256362978235,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}