{"id":"W4238468234","doi":"10.26434/chemrxiv.12551627","title":"Self-Assembly of N-Heterocyclic Carbenes on Au(111)","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Centro Nacional de Processamento de Alto Desempenho em São Paulo; Fundação de Amparo à Pesquisa do Estado de Minas Gerais; Conselho Nacional de Desenvolvimento Científico e Tecnológico","keywords":"Monolayer; Nanotechnology; Ligand (biochemistry); Self-assembly; Thermal stability; Surface modification; Materials science; Metal; Covalent bond; Molecule; Rational design; Annealing (glass); Chemistry; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009870661,0.001046178,0.001404793,0.00007932185,0.0001087468,0.00007428724,0.00175969,0.001415392,0.001140323],"category_scores_gemma":[0.0001787253,0.001112946,0.0008167407,0.0001859319,0.0001779916,0.00006013865,0.001864195,0.00176819,0.0001439254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007376347,"about_ca_system_score_gemma":0.0003199659,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008627613,"about_ca_topic_score_gemma":0.000005511708,"domain_scores_codex":[0.9957028,0.00002662932,0.001166156,0.001593348,0.0007746838,0.0007364086],"domain_scores_gemma":[0.996058,0.0002033642,0.0008784915,0.00229304,0.0001382572,0.0004288011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000108409,0.0003309149,0.0007578689,0.005226651,0.0005755998,0.0000434125,0.0007625614,0.00001380369,0.9893662,0.0001312846,0.002018816,0.0006644445],"study_design_scores_gemma":[0.0007793561,0.00004429702,0.00007642552,0.0005801616,0.0002951763,0.00002641393,0.0001767723,0.0001471992,0.9880714,0.0004767989,0.008366302,0.0009596551],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9076869,0.0006296262,0.00002519075,0.0004070612,0.0008554572,0.0001687484,0.00006817406,0.0006030006,0.08955587],"genre_scores_gemma":[0.9956709,0.000445389,0.0003800209,0.000200191,0.001978957,0.00006371053,0.0002393128,0.0002342869,0.0007872212],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08876865,"threshold_uncertainty_score":0.999881,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01761565712782203,"score_gpt":0.2485151926722824,"score_spread":0.2308995355444604,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}