{"id":"W4238490197","doi":"10.1002/ange.202015450","title":"Asymmetric Hydroesterification of Diarylmethyl Carbinols","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"K. C. Wong Education Foundation; National Natural Science Foundation of China","keywords":"Catalysis; Scope (computer science); Substrate (aquarium); Chemistry; Palladium; Aryl; Enantioselective synthesis; Organic chemistry; Combinatorial chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002182577,0.0005752869,0.0003037311,0.0003304667,0.0001583817,0.0002603606,0.0004377096,0.0003547445,0.002432368],"category_scores_gemma":[0.0002881014,0.0001529263,0.0003078246,0.0002082009,0.0002520836,0.0004672585,0.0005744981,0.0007306004,0.001270056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003379427,"about_ca_system_score_gemma":0.0002492596,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004452723,"about_ca_topic_score_gemma":0.000854556,"domain_scores_codex":[0.999751,0.000027546,0.00002020329,0.00005190459,0.00005015455,0.00009908796],"domain_scores_gemma":[0.9998617,0.00001952394,0.00003327693,0.00002888846,0.0000224669,0.00003420902],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001275375,0.00006574971,0.000163526,0.0001832307,0.00001573038,0.0005130456,0.00009090515,0.000524099,0.9815198,0.001157864,0.0002927287,0.01534586],"study_design_scores_gemma":[0.00001335346,0.00008403255,0.0003214775,0.000006715411,0.000006478171,0.0001325705,0.00001199942,0.0003904656,0.9928339,0.00006519849,0.006125661,0.000008212748],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9269316,0.004393769,0.03890976,0.000345456,0.0003765399,0.0001912026,0.0009162874,0.0004058748,0.02752942],"genre_scores_gemma":[0.9820629,0.001504442,0.007556144,0.00008477997,0.00003873725,0.00003294659,0.000430189,0.00006028898,0.008229513],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002432368,"threshold_uncertainty_score":0.008137107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02556648716853208,"score_gpt":0.2303950099454293,"score_spread":0.2048285227768972,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}