{"id":"W4238490197","doi":"10.1002/ange.202015450","title":"Asymmetric Hydroesterification of Diarylmethyl Carbinols","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"K. C. Wong Education Foundation; National Natural Science Foundation of China","keywords":"Catalysis; Scope (computer science); Substrate (aquarium); Chemistry; Palladium; Aryl; Enantioselective synthesis; Organic chemistry; Combinatorial chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009286442,0.0001529625,0.0003085635,0.00008213089,0.00003326161,0.00001624664,0.000290343,0.0001196753,0.0003662915],"category_scores_gemma":[0.0003992272,0.0001444451,0.0001736081,0.0009234046,0.00004839375,0.00008167817,0.00006325111,0.0001108727,0.00005348487],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003267126,"about_ca_system_score_gemma":0.00002794875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004264597,"about_ca_topic_score_gemma":4.946339e-7,"domain_scores_codex":[0.9988989,0.000008484644,0.0003204919,0.0003073355,0.0002752752,0.0001895751],"domain_scores_gemma":[0.9990944,0.0001433623,0.0001974991,0.0003565418,0.00006586812,0.0001423035],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002115385,0.00006604633,0.003599573,0.0001777021,0.0001033284,0.000004178963,0.0002688607,0.000001545421,0.9425749,0.00004334983,0.001665591,0.05147375],"study_design_scores_gemma":[0.0002186249,0.00001178592,0.0003791737,0.00001364613,0.000089315,0.000001375317,0.0001477085,0.00002867587,0.9815782,0.00002324445,0.01735712,0.0001510678],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5916193,0.00647123,0.0004027132,0.001272168,0.00006380156,0.0001083275,0.0001165476,0.000213042,0.3997329],"genre_scores_gemma":[0.9986783,0.0002749563,0.0002630454,0.0001623904,0.000194625,0.00001818959,0.00007401325,0.00002480126,0.0003096692],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.407059,"threshold_uncertainty_score":0.5890298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02556648716853208,"score_gpt":0.2303950099454293,"score_spread":0.2048285227768972,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}