{"id":"W4239152769","doi":"10.1002/ange.201609726","title":"Development and Cycloaddition Reactivity of a New Class of Pyridine‐Based Mesoionic 1,3‐Dipole","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and Reactivity of Heterocycles","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Centre in Green Chemistry and Catalysis","keywords":"Mesoionic; Pyridine; Cycloaddition; Reactivity (psychology); Quinoline; Chemistry; Dipole; 1,3-Dipolar cycloaddition; Alkyne; Combinatorial chemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002073235,0.000175981,0.0001000165,0.0001850937,0.0001082367,0.0002011029,0.0003149135,0.0001935574,0.001141093],"category_scores_gemma":[0.0002580583,0.00008643781,0.0001129236,0.0001015561,0.0002272389,0.0001996164,0.000217148,0.0003966049,0.0002630792],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002973024,"about_ca_system_score_gemma":0.0001651265,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003419984,"about_ca_topic_score_gemma":0.0004253255,"domain_scores_codex":[0.9999014,0.00001331711,0.000004982366,0.00001794239,0.00003862731,0.00002370398],"domain_scores_gemma":[0.9998896,0.00002080859,0.00003219233,0.0000171821,0.00001709596,0.00002315373],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006161728,0.00003507595,0.0002573319,0.00006208913,0.000006494291,0.00009050758,0.00003821336,0.0005288704,0.9921789,0.001569893,0.0001169427,0.005054126],"study_design_scores_gemma":[0.00001268092,0.0002614306,0.0006823211,0.000003617651,0.000004874506,0.0001758132,0.000009462617,0.0008191377,0.9940255,0.0001018932,0.003895858,0.000007464096],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777304,0.001918923,0.01106294,0.0001396059,0.00003243209,0.00008526711,0.0002344768,0.0001218152,0.008674196],"genre_scores_gemma":[0.9953049,0.0005307996,0.002833301,0.00002456898,0.000004771316,0.00001945105,0.0001082249,0.000009067863,0.001164919],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001141093,"threshold_uncertainty_score":0.003817379,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02519272896062155,"score_gpt":0.2366520646363951,"score_spread":0.2114593356757735,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}