{"id":"W4239180377","doi":"10.1002/ange.201708740","title":"Breaking Bonds and Forming Nanographene Diradicals with Pressure","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Diradical; Raman spectroscopy; Chemistry; Steric effects; Chemical physics; Singlet state; Crystallography; Photochemistry; Computational chemistry; Stereochemistry; Excited state; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001088131,0.0001750877,0.0002355114,0.00001950688,0.0005368562,0.0002740506,0.0003244383,0.00009052177,0.000339286],"category_scores_gemma":[0.00007319191,0.0001259154,0.00004601212,0.00001922092,0.0001988778,0.0002392867,0.0001495166,0.0001040877,0.00000241303],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00000835328,"about_ca_system_score_gemma":0.0000178254,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001055611,"about_ca_topic_score_gemma":0.00002068604,"domain_scores_codex":[0.9991419,0.000003183242,0.0001520166,0.0002574425,0.0001893305,0.0002561095],"domain_scores_gemma":[0.9989941,0.00006523566,0.0001574062,0.0006467089,0.00003065533,0.0001059663],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001478216,0.00008076597,0.04677169,0.0007527532,0.0004031163,0.00004067308,0.000994607,6.825405e-7,0.9100866,0.0001500016,0.002557907,0.03801334],"study_design_scores_gemma":[0.0005081135,0.00002408255,0.00153714,0.0003806317,0.0001014514,0.00005293165,0.0001119404,0.00002173209,0.9408988,0.0003131163,0.05579516,0.000254868],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.844754,0.00218747,0.000008075784,0.000478997,0.00002333742,0.00003989511,0.000009391636,0.00007131263,0.1524275],"genre_scores_gemma":[0.9967991,0.00008797528,0.000657236,0.00005831308,0.0001444339,0.00001914056,0.000004574477,0.00002640282,0.002202844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.152045,"threshold_uncertainty_score":0.5134679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01881601999977424,"score_gpt":0.234785505856678,"score_spread":0.2159694858569038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}