{"id":"W4239277219","doi":"10.1002/ange.200602353","title":"A Melt Approach to the Synthesis of catenaâPhosphorus Dications To Access Derivatives of [P6Ph4R4]2+","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"","keywords":"Chemistry; Phosphorus; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004772186,0.000846479,0.001189537,0.0003091471,0.0003944008,0.0002336027,0.001921509,0.0004123215,0.0001394212],"category_scores_gemma":[0.0007203408,0.0007439198,0.0005082738,0.001823754,0.0003417071,0.0004321584,0.000710454,0.000393615,0.00008318843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002552077,"about_ca_system_score_gemma":0.0002722115,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007957916,"about_ca_topic_score_gemma":0.00002307809,"domain_scores_codex":[0.9953158,0.00008526466,0.001504081,0.001196011,0.001002542,0.0008962274],"domain_scores_gemma":[0.9956384,0.0007181693,0.0008574222,0.001774231,0.0006201514,0.0003915863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000103122,0.0009857593,0.001193524,0.0003009838,0.0003623068,0.000003326769,0.001021095,0.0001900438,0.9840296,0.0001498432,0.003949814,0.007710573],"study_design_scores_gemma":[0.0004646796,0.00003607537,0.005696001,0.0002409452,0.0003118955,0.00001949516,0.0007144418,0.00007096452,0.9866374,0.0001323805,0.004862009,0.0008137255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876275,0.0004136275,0.000957406,0.001603821,0.00008698142,0.0005692303,0.0005813112,0.0001982865,0.007961835],"genre_scores_gemma":[0.9969963,0.0005079317,0.0003192684,0.000480662,0.0004735262,0.0005890251,0.0003353054,0.0001973442,0.0001006214],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009368815,"threshold_uncertainty_score":0.9995012,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01707399795045827,"score_gpt":0.225583938730244,"score_spread":0.2085099407797858,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}