{"id":"W4239898740","doi":"10.1002/ange.201805908","title":"Rhodium‐Catalyzed [4+2+1] Cycloaddition of In Situ Generated Ene/Yne‐Ene‐Allenes and CO","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Peking University; National Natural Science Foundation of China; Ryerson University","keywords":"Ene reaction; Cycloaddition; Rhodium; Chemistry; Catalysis; In situ; Medicinal chemistry; Propargyl; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001144329,0.0002023215,0.0003002714,0.00009381541,0.00006914198,0.00002510053,0.0001413932,0.0001923354,0.000409895],"category_scores_gemma":[0.000117804,0.0002114398,0.00006606781,0.0002134223,0.0002615472,0.0001557269,0.00006817793,0.0001433523,0.00002581219],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001093556,"about_ca_system_score_gemma":0.00007737064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003444995,"about_ca_topic_score_gemma":0.0004970354,"domain_scores_codex":[0.998836,0.000008435184,0.0003450579,0.0003555257,0.0001869403,0.000268054],"domain_scores_gemma":[0.9991111,0.0001174764,0.0001537297,0.0003935167,0.000123476,0.0001007106],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004646458,0.00008258926,0.0009849061,0.00008649177,0.00004441565,0.000007917734,0.0003278514,5.283563e-7,0.9944679,0.00002388446,0.003123027,0.0008039811],"study_design_scores_gemma":[0.000913844,0.00001323101,0.0007856329,0.00007602696,0.00004122335,0.00003324033,0.0002038873,0.00001448332,0.9864513,0.0001255255,0.01112574,0.0002159157],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9549801,0.0003342514,0.00001224782,0.0001303636,0.00005603099,0.00006281691,0.0001311832,0.00006975614,0.04422323],"genre_scores_gemma":[0.9975289,0.0002678772,0.0001449424,0.00003966583,0.0003395132,0.0000295693,0.0005679066,0.00003036997,0.001051233],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.043172,"threshold_uncertainty_score":0.8622265,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01806037698916651,"score_gpt":0.2603899442728848,"score_spread":0.2423295672837182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}