{"id":"W4239898740","doi":"10.1002/ange.201805908","title":"Rhodium‐Catalyzed [4+2+1] Cycloaddition of In Situ Generated Ene/Yne‐Ene‐Allenes and CO","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Peking University; National Natural Science Foundation of China; Ryerson University","keywords":"Ene reaction; Cycloaddition; Rhodium; Chemistry; Catalysis; In situ; Medicinal chemistry; Propargyl; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001892847,0.0006467168,0.0002110086,0.0002381224,0.0002184161,0.0002724488,0.0003944684,0.0003038812,0.003188147],"category_scores_gemma":[0.000164802,0.0002263949,0.0002129868,0.0001121872,0.0002343312,0.0003531966,0.0002999908,0.000565499,0.001078266],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003821862,"about_ca_system_score_gemma":0.00041735,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007701214,"about_ca_topic_score_gemma":0.002530793,"domain_scores_codex":[0.9998323,0.00002923579,0.000009959849,0.00003037578,0.00003601263,0.00006205233],"domain_scores_gemma":[0.999929,0.000009703873,0.00001974554,0.00001625186,0.0000111113,0.00001422142],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001300666,0.000121595,0.0002525294,0.0002463988,0.00004451487,0.0005967316,0.0001116152,0.0007987321,0.982027,0.004420398,0.000723561,0.01052698],"study_design_scores_gemma":[0.000008758341,0.00009958335,0.0002290453,0.000004398808,0.00001033287,0.0001497909,0.0000140058,0.0004280909,0.9927216,0.00007974284,0.006246267,0.000008483429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9037567,0.002002481,0.03091166,0.0004967839,0.0003951572,0.0002816548,0.0003908768,0.0004557076,0.06130902],"genre_scores_gemma":[0.984777,0.000740196,0.0067504,0.00005917883,0.00002345179,0.00004541143,0.0001718679,0.00003660902,0.007395821],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003188147,"threshold_uncertainty_score":0.01066536,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01806037698916651,"score_gpt":0.2603899442728848,"score_spread":0.2423295672837182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}