{"id":"W4240041713","doi":"10.1016/j.chroma.2004.07.103","title":"Pulsed discharge detector: theory and applications","year":2004,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"Health Canada","funders":"","keywords":"Thermal conductivity detector; Helium ionization detector; Discharge ionization detector; Detector; Chemistry; Ionization; Flame ionization detector; Helium; Gas chromatography; Electron capture detector; Analytical Chemistry (journal); Sensitivity (control systems); Nuclear engineering; Chromatography; Optics; Ion; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009239097,0.0007093759,0.001279633,0.001032936,0.0006882085,0.002139993,0.003338455,0.003065681,0.002773031],"category_scores_gemma":[0.001611335,0.0007613639,0.000714156,0.002157749,0.001625729,0.002443915,0.001480657,0.003002915,0.001830673],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008980343,"about_ca_system_score_gemma":0.0008753893,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002659208,"about_ca_topic_score_gemma":0.0002028571,"domain_scores_codex":[0.9991099,0.0001586163,0.00002838919,0.0002027305,0.0004460795,0.00005430035],"domain_scores_gemma":[0.9992663,0.0003828192,0.00004225208,0.00008820966,0.0001797743,0.00004057526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001250325,0.0001787462,0.0009628763,0.0007185378,0.00009707101,0.000434098,0.0002219984,0.04254375,0.05862738,0.6729912,0.01664508,0.2064543],"study_design_scores_gemma":[0.00003818789,0.0001608207,0.0005125604,0.00009500221,0.00005988235,0.00166657,0.00008614018,0.6312473,0.02245769,0.291512,0.05205143,0.0001124131],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.002456066,0.005608097,0.9841079,0.0006946285,0.0002661663,0.00003115403,0.00005615924,0.0003846813,0.006395063],"genre_scores_gemma":[0.2899964,0.02059067,0.6595284,0.002166983,0.001900589,0.0004611509,0.0004305125,0.0003014014,0.02462388],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.003338455,"threshold_uncertainty_score":0.009276688,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00521904110921928,"score_gpt":0.2402090459430196,"score_spread":0.2349900048338004,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}