{"id":"W4240081353","doi":"10.1002/ange.201605754","title":"Synthesis of Aminoboronic Acid Derivatives from Amines and Amphoteric Boryl Carbonyl Compounds","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research","keywords":"Chemistry; Iminium; Conjugated system; Tautomer; Molecule; Combinatorial chemistry; Boron; Organic chemistry; Condensation; Ion; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004789363,0.0003292527,0.0004738918,0.00003421696,0.0000613241,0.0000275723,0.0003048704,0.0002302278,0.001879461],"category_scores_gemma":[0.000200547,0.0002511788,0.0001008366,0.0001054028,0.0003926225,0.0001382267,0.0001618935,0.0001050361,0.00001242574],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009460013,"about_ca_system_score_gemma":0.00004924783,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009370691,"about_ca_topic_score_gemma":0.00002196084,"domain_scores_codex":[0.9985719,0.00001110296,0.0003647936,0.0004900969,0.0002213762,0.0003407821],"domain_scores_gemma":[0.9986464,0.0003714956,0.0002023308,0.0005492836,0.00006723797,0.000163221],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003934761,0.00006176239,0.0178525,0.0001573793,0.0001044162,0.000007193113,0.0001883614,1.074005e-8,0.9779514,0.000006918298,0.0004212029,0.00320949],"study_design_scores_gemma":[0.000727278,0.00001364664,0.004072465,0.0002247763,0.00007611687,0.000009367535,0.0002310127,6.994433e-7,0.9929324,0.0001002906,0.001267553,0.0003443967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913354,0.002186801,0.000008486869,0.0003396088,0.00005192377,0.00003499514,0.0003378047,0.0001132042,0.005591791],"genre_scores_gemma":[0.9982109,0.0007537263,0.0001951996,0.00006358811,0.0002120418,0.00001974076,0.00002275533,0.00005299906,0.0004690516],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01498098,"threshold_uncertainty_score":0.999994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01115023057112127,"score_gpt":0.2158436999722296,"score_spread":0.2046934694011084,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}