{"id":"W4240550269","doi":"10.1002/cphc.201600116","title":"High‐Pressure Raman and Calorimetry Studies of Vanadium(III) Alkyl Hydrides for Kubas‐Type Hydrogen Storage","year":2016,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Hydro-Québec","funders":"Engineering and Physical Sciences Research Council","keywords":"Vanadium; Hydride; Calorimetry; Raman spectroscopy; Hydrogen storage; Alkyl; Amorphous solid; Chemistry; Hydrogen; Physical chemistry; Materials science; Inorganic chemistry; Crystallography; Chemical engineering; Organic chemistry; Thermodynamics; Physics; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002319127,0.0001966055,0.0001304655,0.0002193952,0.0002279055,0.0002912381,0.0003265743,0.0002294203,0.001350182],"category_scores_gemma":[0.0002321674,0.0001834612,0.0001222368,0.0001884766,0.0003733035,0.0002374104,0.000219094,0.0002926206,0.0002380457],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002926853,"about_ca_system_score_gemma":0.0001484371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001257106,"about_ca_topic_score_gemma":0.002040053,"domain_scores_codex":[0.9998865,0.00001343608,0.000004452736,0.00001379734,0.00005582321,0.00002605361],"domain_scores_gemma":[0.9999063,0.00003357824,0.0000147214,0.000007463635,0.00002852617,0.000009400627],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008437752,0.00001243475,0.0001856483,0.00003975883,0.000004312495,0.00003870718,0.00008623691,0.000331724,0.9972567,0.0002806007,0.0001070614,0.001572404],"study_design_scores_gemma":[0.000004868122,0.00007181323,0.001254051,0.000003438937,0.000003249103,0.00003755372,0.00008836431,0.002373766,0.9956276,0.00004994122,0.0004771861,0.000008120632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967836,0.0004390304,0.0008976673,0.000055695,0.00001211838,0.000009314086,0.0001131296,0.00002979405,0.00165947],"genre_scores_gemma":[0.998253,0.0001906372,0.0006594837,0.000007399522,0.000003307262,0.00000596219,0.00005323878,0.00000788841,0.0008189678],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001350182,"threshold_uncertainty_score":0.00451684,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02840475470564081,"score_gpt":0.2798682627474353,"score_spread":0.2514635080417945,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}