{"id":"W4241026824","doi":"10.1002/ange.202103965","title":"Near‐Infrared‐Emitting Boron‐Difluoride‐Curcuminoid‐Based Polymers Exhibiting Thermally Activated Delayed Fluorescence as Biological Imaging Probes","year":2021,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polymer; Photochemistry; Fluorescence; Chemistry; Polymerization; Photoluminescence; Curcuminoid; Hypsochromic shift; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000645998,0.0005349627,0.0005958729,0.00006898321,0.0005468875,0.0006235451,0.0006121228,0.0002358254,0.003213855],"category_scores_gemma":[0.0007422548,0.0004598005,0.0002048088,0.0003757357,0.0003964859,0.0006395547,0.0003413843,0.0002759763,0.0003092854],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001386736,"about_ca_system_score_gemma":0.0005022662,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002241341,"about_ca_topic_score_gemma":0.000005045709,"domain_scores_codex":[0.996272,0.000185102,0.0007574444,0.001082005,0.0005530145,0.001150459],"domain_scores_gemma":[0.9981022,0.0002329785,0.0003723646,0.0006739305,0.0003260982,0.0002923969],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001494188,0.0001303132,0.003834609,0.00008066291,0.0000200229,0.0003772325,0.0004570189,0.000009494016,0.9932764,0.00002900968,0.0007163417,0.0009195445],"study_design_scores_gemma":[0.0008474538,0.00005344632,0.0006825209,0.0002843136,0.00004358304,0.00009729634,0.0005705685,0.0001054611,0.9955544,0.00006456547,0.001077419,0.0006189015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929776,0.0007552245,0.00006500146,0.0006371428,0.0005458827,0.000323163,0.00006570936,0.0004609109,0.004169379],"genre_scores_gemma":[0.9933038,0.00004876583,0.004035487,0.001260579,0.000471082,0.00006347163,0.0002115675,0.00007014914,0.0005350812],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003970486,"threshold_uncertainty_score":0.9997854,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01741976645388865,"score_gpt":0.2499760186793653,"score_spread":0.2325562522254766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}