{"id":"W4241302167","doi":"10.1002/ange.201800361","title":"Chemoselective Synthesis of <i>Z</i>‐Olefins through Rh‐Catalyzed Formate‐Mediated 1,6‐Reduction","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Electrophile; Chemistry; Stereoselectivity; Formic acid; Catalysis; Formate; Chemoselectivity; Functional group; Electrophilic addition; Alkene; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001419566,0.000236228,0.0003681497,0.0001058771,0.0001310167,0.00002058873,0.0002769631,0.0002162906,0.001777706],"category_scores_gemma":[0.0003736683,0.0002272706,0.0001914309,0.0009617876,0.0002373361,0.0002904158,0.00007215485,0.0001407535,0.000207477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001340647,"about_ca_system_score_gemma":0.00007748697,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001154995,"about_ca_topic_score_gemma":0.00001094619,"domain_scores_codex":[0.9985175,0.00001058581,0.0004203863,0.000355806,0.0003616744,0.0003340449],"domain_scores_gemma":[0.9987162,0.0001165504,0.0003018579,0.0004388561,0.0003293196,0.00009725435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007261102,0.0001597283,0.0002250603,0.00009251597,0.0002481484,0.000001559272,0.0009367425,4.838015e-7,0.9929789,0.00005646946,0.003338675,0.001889104],"study_design_scores_gemma":[0.0004939565,0.00001408607,0.0000278793,0.00003093111,0.0001435098,0.00001813534,0.0006799463,0.00002717722,0.9885987,0.000138484,0.00958201,0.0002451579],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7861719,0.0002775209,0.0001936406,0.000174329,0.0001021065,0.00008396429,0.0001390384,0.0002101889,0.2126473],"genre_scores_gemma":[0.9978883,0.0001487295,0.000317506,0.00008206435,0.0002830798,0.00005146682,0.0002915098,0.00003658757,0.0009007411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2117466,"threshold_uncertainty_score":0.9991348,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01310673391789463,"score_gpt":0.240562470905076,"score_spread":0.2274557369871814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}