{"id":"W4241349066","doi":"10.1139/cjc-78-9-1178","title":"Acidity constants and reactivities of the benzidine and <i>N</i>,<i>N</i>-dimethylbenzidine dications, the two electron o×idation intermediates of benzidine carcinogens","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Benzidine; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004164104,0.0003067509,0.0001392328,0.0005437052,0.0001886207,0.0001892264,0.0003644966,0.0002353177,0.007251139],"category_scores_gemma":[0.001011446,0.000235657,0.0001726367,0.0002254024,0.0002431093,0.0003041357,0.0001770488,0.000337049,0.001013569],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006313265,"about_ca_system_score_gemma":0.0003381659,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005594725,"about_ca_topic_score_gemma":0.00532012,"domain_scores_codex":[0.9998531,0.00001950229,0.000006824842,0.00003044364,0.0000379547,0.00005218657],"domain_scores_gemma":[0.9995271,0.0002104282,0.00006489646,0.00002218164,0.0001218017,0.00005354762],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.001633993,0.00006078797,0.003159694,0.0001599396,0.00003568275,0.0001095705,0.0002427429,0.003750886,0.9731323,0.003237965,0.0003437136,0.01413269],"study_design_scores_gemma":[0.00002788992,0.0002367437,0.006561546,0.000009653667,0.00002025354,0.00005744287,0.0000561921,0.002130005,0.988416,0.0003567986,0.002104688,0.00002278589],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9846143,0.00211575,0.004923371,0.00005960817,0.00002529528,0.00003656853,0.0006297351,0.0000564341,0.007538844],"genre_scores_gemma":[0.9931351,0.0009962277,0.00115784,0.00001862475,0.00000921949,0.00002778991,0.0009442734,0.00001835479,0.003692436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007251139,"threshold_uncertainty_score":0.02425748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00872755207653164,"score_gpt":0.2186154415517676,"score_spread":0.2098878894752359,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}