{"id":"W4241535041","doi":"10.1002/ange.201912338","title":"Single Electron Transfer to Diazomethane–Borane Adducts Prompts C−H Bond Activations","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Technische Universität Berlin; Leibniz-Gemeinschaft; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Adduct; Borane; Diazomethane; Electron transfer; Medicinal chemistry; Photochemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001440631,0.000269968,0.0001728627,0.0001273752,0.0002413255,0.0001984499,0.0002908231,0.0003296068,0.00581478],"category_scores_gemma":[0.0002135603,0.0001465978,0.000109247,0.00007998879,0.0002331881,0.0002767974,0.0002441567,0.0006252457,0.0005245541],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003225583,"about_ca_system_score_gemma":0.0002123347,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005653393,"about_ca_topic_score_gemma":0.001085254,"domain_scores_codex":[0.9998578,0.00001082593,0.000003526315,0.00003202986,0.00003148965,0.00006426517],"domain_scores_gemma":[0.9998977,0.0000297621,0.00001539023,0.00001987827,0.000009616154,0.00002756116],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001391018,0.00002194287,0.0001403945,0.00004452129,0.000007010314,0.0001494344,0.00005512209,0.00008681248,0.9969051,0.000519335,0.0001902216,0.001741009],"study_design_scores_gemma":[0.00001806998,0.0001128501,0.0006273717,0.000001958718,0.000002380099,0.0001114939,0.00001581793,0.0003470717,0.9976041,0.0001131198,0.00104141,0.000004428903],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870625,0.0003092678,0.003760349,0.0001726495,0.0000827381,0.00005010849,0.000172764,0.0001706955,0.008218921],"genre_scores_gemma":[0.9976729,0.00005785695,0.0006339619,0.00003325434,0.000004283918,0.000009170429,0.00005463605,0.00001251977,0.001521517],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00581478,"threshold_uncertainty_score":0.01945239,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01343003835130755,"score_gpt":0.2346543663387846,"score_spread":0.2212243279874771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}