{"id":"W4241571479","doi":"10.1002/ange.201101773","title":"Rhodium‐Catalyzed Domino Enantioselective Synthesis of Bicyclo[2.2.2]lactones","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Enantioselective synthesis; Chemistry; Rhodium; Bicyclic molecule; Domino; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002462369,0.0005905306,0.0003361483,0.0002546825,0.0001482966,0.0002500868,0.0003380458,0.0002514458,0.001509226],"category_scores_gemma":[0.0002033678,0.0001788263,0.0001961654,0.0002798682,0.000171219,0.0002608394,0.0003201658,0.000422427,0.0006762536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003548079,"about_ca_system_score_gemma":0.0004450597,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008793708,"about_ca_topic_score_gemma":0.002120344,"domain_scores_codex":[0.9998288,0.00003267096,0.00001321799,0.00002318316,0.0000290874,0.00007296202],"domain_scores_gemma":[0.9999442,0.000008414661,0.000009800016,0.0000115133,0.00001063817,0.0000154491],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000180895,0.0000606923,0.0001209196,0.0001854573,0.00001431296,0.0003039255,0.0001287338,0.0009457449,0.9887571,0.001245743,0.0004071874,0.007649303],"study_design_scores_gemma":[0.00004987183,0.0002521492,0.0005261293,0.000008915395,0.00001372804,0.0001543952,0.00003478193,0.0008643706,0.9896724,0.000134622,0.008268595,0.00002007455],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9656479,0.003586017,0.008985629,0.0002758932,0.0001412002,0.0001834026,0.0008066931,0.0002888511,0.02008444],"genre_scores_gemma":[0.9876273,0.001158712,0.005266937,0.00007403831,0.00001204171,0.00006105636,0.0003334469,0.00004138998,0.005425056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001509226,"threshold_uncertainty_score":0.005048871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02245608763125017,"score_gpt":0.2293643754969971,"score_spread":0.206908287865747,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}