{"id":"W4241751967","doi":"10.26434/chemrxiv.13619180","title":"Aminobismuthination of CO2","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Dalhousie University; Compute Canada; Nova Scotia Research Innovation Trust","keywords":"Bismuth; Substituent; Chemistry; Ligand (biochemistry); Thermal decomposition; Yield (engineering); Carbamate; Decomposition; Medicinal chemistry; Rendering (computer graphics); Stereochemistry; Materials science; Organic chemistry; Computer science; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008755283,0.0004172094,0.0001713665,0.000138469,0.0001799096,0.0001726218,0.0002932017,0.0002557766,0.001651688],"category_scores_gemma":[0.0001478691,0.00008713762,0.0001011123,0.0001653976,0.0001573617,0.0002726584,0.0002814037,0.000325909,0.0005804481],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002407803,"about_ca_system_score_gemma":0.0001645384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001266651,"about_ca_topic_score_gemma":0.002117781,"domain_scores_codex":[0.9998411,0.00001731571,0.000009110459,0.00004466195,0.00004365499,0.00004417017],"domain_scores_gemma":[0.9999262,0.00000784166,0.00002277808,0.0000117547,0.0000190884,0.00001239822],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001217987,0.00002296066,0.0001524972,0.00009954402,0.000009192688,0.0001288445,0.00005614227,0.0001033969,0.9942185,0.0004569319,0.0001880099,0.004442105],"study_design_scores_gemma":[0.000002228717,0.00005963114,0.0002540636,0.000001503248,0.000002548267,0.00008201395,0.000005948089,0.0002213173,0.9970799,0.000016277,0.002272013,0.000002619308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9807476,0.001569738,0.005297272,0.0001577772,0.000107117,0.0000331469,0.0002031979,0.0001662379,0.01171794],"genre_scores_gemma":[0.9935209,0.0004971912,0.001578544,0.00003934016,0.00001383855,0.00001181812,0.0001919422,0.00005045406,0.004095891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001651688,"threshold_uncertainty_score":0.00552541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01674597900597126,"score_gpt":0.2467539738808772,"score_spread":0.230007994874906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}