{"id":"W4241865796","doi":"10.22215/etd/2009-06444","title":"Development of tetraphenylborate-based photobase generators and sacrificial polycarbonates for radiation curing and photoresist applications","year":2009,"lang":"en","type":"dissertation","venue":"","topic":"Photopolymerization techniques and applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; Canadian Heritage; Library and Archives Canada","funders":"","keywords":"Photoresist; Tetraphenylborate; Curing (chemistry); Materials science; Chemistry; Nanotechnology; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00007261705,0.000268399,0.000290965,0.000154767,0.0002724646,0.00004822034,0.0001173033,0.0002622296,0.0000937529],"category_scores_gemma":[0.00001292078,0.0002903516,0.00005744188,0.0001784056,0.00004022967,0.000044642,0.000007799484,0.00009820887,2.495929e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000391894,"about_ca_system_score_gemma":0.0002336848,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004340152,"about_ca_topic_score_gemma":0.000101776,"domain_scores_codex":[0.998732,0.000005299989,0.0005400378,0.0004107117,0.0001487606,0.0001632287],"domain_scores_gemma":[0.9991456,0.00005278431,0.0003731002,0.0002141259,0.000119815,0.00009463317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006002118,0.0001226948,0.0001012358,0.0005097521,0.0000394461,9.633681e-8,0.0001645157,0.00000108933,0.8893729,0.001705365,0.00004723729,0.1078756],"study_design_scores_gemma":[0.0003439531,0.00001002541,0.0002725569,0.00005686717,0.00006838798,3.040417e-7,0.0002303648,0.000592955,0.990187,0.0004550022,0.00748508,0.0002975371],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9802059,0.002128493,0.01140276,0.00003208766,0.00003798743,0.001455982,0.0004800707,0.0002845737,0.003972145],"genre_scores_gemma":[0.9300692,0.000295164,0.05885869,0.00007351336,0.0001062109,0.002957301,0.007216108,0.00007308018,0.0003507322],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1075781,"threshold_uncertainty_score":0.9999549,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00791168381176208,"score_gpt":0.2592211122268571,"score_spread":0.251309428415095,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}