{"id":"W4241887327","doi":"10.1139/cjc-79-5-6-598","title":"Studies on transition-metal nitrido and oxo complexes. Part 20. Oxoruthenates and oxo-osmates in oxidation catalysis; <i>cis</i>-[Os(OH)<sub>2</sub>O<sub>4</sub>]<sup>2-</sup> as a catalytic oxidant for primary amines and for alcohols","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Transition metal; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001582585,0.002395897,0.0033095,0.0008790778,0.001485472,0.0007856896,0.001340822,0.001324152,0.0003916389],"category_scores_gemma":[0.002319,0.002555537,0.0009964921,0.001336596,0.001835595,0.001295267,0.0002675978,0.001465215,0.00003322927],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002377793,"about_ca_system_score_gemma":0.002053922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001116946,"about_ca_topic_score_gemma":0.004993804,"domain_scores_codex":[0.989562,0.0001654035,0.003568695,0.002498673,0.001540464,0.002664705],"domain_scores_gemma":[0.9895455,0.001932805,0.002326173,0.001601092,0.001812237,0.002782232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008378595,0.0005742826,0.0004402604,0.002522889,0.002055758,0.0005692476,0.001866167,0.0001804384,0.9804174,0.00007030173,0.008739931,0.001725503],"study_design_scores_gemma":[0.007958309,0.0003458103,0.0008179371,0.002024261,0.002038034,0.00374301,0.001525463,0.0007522384,0.9510005,0.0009368752,0.02613534,0.002722246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9751655,0.0156435,0.0001009237,0.002163131,0.0003471726,0.001307652,0.003060365,0.0001766166,0.002035087],"genre_scores_gemma":[0.9879041,0.004013517,0.0005020189,0.0003073589,0.001665676,0.0004082373,0.002875479,0.0004529312,0.001870672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02941689,"threshold_uncertainty_score":0.9999723,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01853031726718337,"score_gpt":0.2422155837470605,"score_spread":0.2236852664798771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}