{"id":"W4241973942","doi":"10.26434/chemrxiv.12049083.v1","title":"Synthesis, Characterization and Reactivity of Neutral Octahedral Alkyl-Cobalt(III) Complexes Bearing a Dianionic Pendadentate Ligand","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates","keywords":"Chemistry; Protonation; Homolysis; Ligand (biochemistry); Heterolysis; Alkyl; Reactivity (psychology); Medicinal chemistry; Octahedron; Octahedral molecular geometry; Bond cleavage; Cobalt; Stereochemistry; Crystallography; Crystal structure; Inorganic chemistry; Organic chemistry; Radical; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001298013,0.0002460038,0.0002584257,0.0001817438,0.0001346651,0.0004333871,0.0002928383,0.0002184675,0.0006409163],"category_scores_gemma":[0.0002446908,0.0001381114,0.00009133195,0.0002104389,0.0002043642,0.0001562402,0.0002298667,0.0002585758,0.0002415617],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003429366,"about_ca_system_score_gemma":0.0001409195,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007831529,"about_ca_topic_score_gemma":0.001231168,"domain_scores_codex":[0.9998487,0.00001670966,0.0000161736,0.00003019403,0.00005850777,0.00002959924],"domain_scores_gemma":[0.9998503,0.00002386599,0.00003788779,0.00001926103,0.00003706314,0.00003156922],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009164119,0.00001013621,0.0002282955,0.00004877165,0.000006095227,0.00004053713,0.00002294629,0.00006177279,0.9981646,0.00005768894,0.00002668155,0.001240903],"study_design_scores_gemma":[0.000007015296,0.0001158034,0.0007633225,0.000002063768,0.000009103836,0.0001077854,0.00001117314,0.0002262123,0.9975547,0.00001120156,0.00118792,0.000003650156],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948853,0.0007898332,0.00239682,0.00003048391,0.000009483898,0.00002542878,0.0002035714,0.00006416885,0.001594901],"genre_scores_gemma":[0.9957809,0.0004794347,0.001888373,0.00001927111,0.000004072699,0.00001924653,0.0004071198,0.00003112735,0.001370342],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007831529,"threshold_uncertainty_score":0.002488196,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02618988582947588,"score_gpt":0.2405088377980531,"score_spread":0.2143189519685772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}