{"id":"W4242964389","doi":"10.1002/ange.201806640","title":"A Stable Crown Ether Complex with a Noble‐Gas Compound","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Crown ether; Xenon; Noble gas; Denticity; Ether; Adduct; Crystallography; Ligand (biochemistry); Oxygen atom; 18-Crown-6; Crystal structure; Molecule; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001234828,0.0002898684,0.0002932597,0.00003501286,0.0002877608,0.0001063553,0.0003333473,0.0002105965,0.009159492],"category_scores_gemma":[0.0000131709,0.000223278,0.00007914208,0.0002238223,0.0003396634,0.0001063649,0.0001046946,0.0003202935,0.0003298651],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001296059,"about_ca_system_score_gemma":0.0001010163,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001774859,"about_ca_topic_score_gemma":0.00005234712,"domain_scores_codex":[0.9985169,0.00001006466,0.0002390588,0.0004048928,0.0002897955,0.0005392746],"domain_scores_gemma":[0.9989294,0.00006472618,0.0001083438,0.0005630578,0.0001849297,0.0001494943],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004215201,0.0001182691,0.0004442711,0.00006477552,0.0001857458,0.00005019287,0.0006301103,0.000002253006,0.9742371,0.0001873515,0.02353878,0.0001195921],"study_design_scores_gemma":[0.001035657,0.0001000662,0.00004747089,0.00007425534,0.00005077828,0.0001160284,0.0001790867,0.00004930598,0.7640812,0.0002201591,0.2337456,0.0003003734],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.724739,0.0002362048,0.00006248087,0.0004669393,0.0001060491,0.00006493758,0.00002241166,0.0002308752,0.2740712],"genre_scores_gemma":[0.9822814,0.00001847037,0.00102376,0.0003950128,0.0006080904,0.00001315172,0.00005209937,0.00007288589,0.01553511],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.258536,"threshold_uncertainty_score":0.9917462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01895822988650435,"score_gpt":0.2321682967790116,"score_spread":0.2132100668925073,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}