{"id":"W4243790714","doi":"10.1139/v07-013","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part VIII. Synthesis and characterization of a series of 1,4-di[2-aryl-1-diazenyl]-2-methylpiperazines<sup>1</sup>","year":2007,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Piperazine; Heteronuclear single quantum coherence spectroscopy; Methylene; Ring (chemistry); DEPT; Aryl; Proton NMR; Proton; Spectroscopy; Nuclear magnetic resonance spectroscopy; Carbon-13 NMR; NMR spectra database; Two-dimensional nuclear magnetic resonance spectroscopy; Stereochemistry; Crystallography; Spectral line; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008373756,0.0003549989,0.0002588444,0.0001881112,0.00009406755,0.0002073826,0.0003370074,0.0002825893,0.002209374],"category_scores_gemma":[0.000180614,0.0001427977,0.0002036008,0.000201545,0.0001648204,0.000191864,0.000196488,0.0004469972,0.0006998305],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002448969,"about_ca_system_score_gemma":0.0001507199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002909332,"about_ca_topic_score_gemma":0.0005690012,"domain_scores_codex":[0.999885,0.00001940207,0.0000100123,0.00002030041,0.00003123594,0.00003408354],"domain_scores_gemma":[0.9999107,0.00001074496,0.00003221352,0.00001052404,0.00001511792,0.00002071303],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006626919,0.00001975937,0.00005453729,0.0000721826,0.000005032201,0.00004507411,0.00001205452,0.0000792628,0.9977155,0.0001063331,0.00006056968,0.001763513],"study_design_scores_gemma":[0.00002002085,0.0006220035,0.001042698,0.000008530181,0.00001661903,0.0001907313,0.0000169542,0.0002609233,0.9919547,0.00004135906,0.005820067,0.000005438747],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9749624,0.005614936,0.006950459,0.0001767288,0.0001049328,0.0001149939,0.0008435668,0.0002781717,0.01095385],"genre_scores_gemma":[0.9767929,0.004090161,0.00828207,0.0001308659,0.00002574882,0.0001194017,0.0009681257,0.0000665514,0.009524126],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002209374,"threshold_uncertainty_score":0.007391036,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009241154890602876,"score_gpt":0.2058126119893621,"score_spread":0.1965714570987593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}