{"id":"W4243901502","doi":"10.13179/canchemtrans.2014.02.04.0124","title":"Synthesis, Spectral, Stereochemical and Antimicrobial Evaluation of Some 3t-pentyl-2r,6c-diarylpiperidin-4-one Thiosemicarbazone Derivatives","year":2014,"lang":"en","type":"article","venue":"Canadian Chemical Transactions","topic":"Synthesis and biological activity","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"","keywords":"Semicarbazone; Antimicrobial; Stereochemistry; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003718466,0.000274512,0.0004737188,0.000091147,0.0001384362,0.00003858413,0.0002404172,0.0003547425,0.002368396],"category_scores_gemma":[0.0004749651,0.0002623442,0.0001736395,0.0001517272,0.0003923193,0.0001627326,0.00001272019,0.0003538518,0.00001037108],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002420501,"about_ca_system_score_gemma":0.0001849123,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002207353,"about_ca_topic_score_gemma":0.001178599,"domain_scores_codex":[0.9982204,0.00009245607,0.0003775345,0.0005253878,0.0003120234,0.0004721977],"domain_scores_gemma":[0.9984151,0.0005571466,0.0001078236,0.0003288551,0.0001129395,0.0004781791],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003073683,0.0001659891,0.0002312844,0.00007452038,0.00009094509,6.868615e-7,0.0000476464,0.000003837877,0.9836876,0.0001701931,0.00008927673,0.01540727],"study_design_scores_gemma":[0.0004249077,0.00001277221,0.0005747373,0.0001074403,0.0002261522,0.00001524626,0.00004863657,0.0006195923,0.9961531,0.0008343358,0.0006629974,0.0003200885],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939159,0.0001482928,0.000317717,0.001084077,0.00005964606,0.0001396385,0.0002493419,0.00005460601,0.004030833],"genre_scores_gemma":[0.9988682,0.0001010902,0.0005443005,0.0001330577,0.0002058852,0.00005195554,0.00003833406,0.00002593534,0.00003125299],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01508718,"threshold_uncertainty_score":0.9999829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03053775458862977,"score_gpt":0.2326202279015904,"score_spread":0.2020824733129606,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}