{"id":"W4243953015","doi":"10.1021/jp991715v","title":"Mechanism of Silation of Silica with Hexamethyldisilazane","year":2000,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Hexamethyldisiloxane; Silylation; Chemistry; Methane; Ammonia; Nitrogen; Reaction mechanism; Organic chemistry; Polymer chemistry; Inorganic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000167221,0.0005491964,0.0002252973,0.0002508489,0.0001753778,0.0001902378,0.000392707,0.0003124284,0.00219996],"category_scores_gemma":[0.000165139,0.000231091,0.0004577935,0.00007457102,0.0002691367,0.0003322949,0.0003043262,0.0002311194,0.0005178697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002372696,"about_ca_system_score_gemma":0.000142269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000438503,"about_ca_topic_score_gemma":0.0005606571,"domain_scores_codex":[0.9998882,0.00001203358,0.000005190456,0.00002330013,0.00003307677,0.00003826255],"domain_scores_gemma":[0.9998962,0.00002444832,0.0000374655,0.000009060377,0.00001612643,0.00001678619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008870556,0.00001447025,0.000423483,0.0001701574,0.00002691917,0.0002744174,0.000049543,0.0004873658,0.9959369,0.0003728418,0.00009312536,0.002062093],"study_design_scores_gemma":[0.00001025542,0.0001507703,0.001548054,0.000006314651,0.00001163878,0.0002766843,0.00001873056,0.001129142,0.9952592,0.0001110513,0.001471423,0.00000673161],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9798964,0.003743004,0.009547173,0.0001718306,0.0000926329,0.0001116164,0.0002315395,0.0001634069,0.006042412],"genre_scores_gemma":[0.9929848,0.001212572,0.001948945,0.00005293817,0.00001479237,0.00003076671,0.0001197907,0.00001438513,0.00362099],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00219996,"threshold_uncertainty_score":0.007359564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007153565863721356,"score_gpt":0.2215454792520818,"score_spread":0.2143919133883605,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}