{"id":"W4243978186","doi":"10.1002/ange.201008079","title":"Total Synthesis of Pactamycin","year":2011,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Total synthesis; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009154724,0.0007751154,0.0003242633,0.0003622667,0.0002881108,0.0003684258,0.0002721025,0.0002603914,0.004756304],"category_scores_gemma":[0.0001578823,0.000140266,0.0002262779,0.0007221895,0.0001369995,0.00033918,0.0003781248,0.000745491,0.002388001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003815086,"about_ca_system_score_gemma":0.000767578,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008627324,"about_ca_topic_score_gemma":0.001191026,"domain_scores_codex":[0.9998746,0.00001286646,0.000009852794,0.00003407554,0.00003620621,0.00003226592],"domain_scores_gemma":[0.9999348,0.000006506869,0.00001046178,0.00001168589,0.00001895082,0.00001762063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00014329,0.00004044244,0.000083477,0.0002410418,0.00001686472,0.000160522,0.00003705333,0.0005557316,0.977498,0.0007074379,0.0004156874,0.02010035],"study_design_scores_gemma":[0.00002855386,0.0003009401,0.0006285734,0.00002006631,0.00002680216,0.0002267948,0.00001889336,0.0006676497,0.9636987,0.0003076594,0.03406422,0.00001109125],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7081467,0.01428431,0.1888287,0.0006671631,0.0006807157,0.001278643,0.01663476,0.002952774,0.06652629],"genre_scores_gemma":[0.9010091,0.00635916,0.0481655,0.0002231048,0.00005097692,0.0004673778,0.01092971,0.0004453887,0.03234959],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004756304,"threshold_uncertainty_score":0.0159114,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02616219004741764,"score_gpt":0.2309698055563975,"score_spread":0.2048076155089799,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}