{"id":"W4244155963","doi":"10.1002/chin.200503250","title":"Carbocations","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Medicinal chemistry; Computational chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00001976765,0.00008171918,0.00006893762,0.00001473788,0.00003809494,0.0000155179,0.000126485,0.0000850626,0.00185498],"category_scores_gemma":[0.00008794689,0.00008211183,0.0000518657,0.00007881033,0.00002532943,0.00008255582,0.00003133265,0.0001200626,0.0003595669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002012583,"about_ca_system_score_gemma":0.00005903026,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001972137,"about_ca_topic_score_gemma":0.000002192137,"domain_scores_codex":[0.9994774,1.18483e-8,0.0001281501,0.0001075121,0.0001320619,0.0001547925],"domain_scores_gemma":[0.9995695,0.0000170942,0.00003880808,0.0002434448,0.00003415507,0.00009701661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003998097,0.00004176419,0.000006087771,0.00003673481,0.00001101493,0.000002164004,0.0002005816,0.000002024154,0.9485664,0.008600458,0.001064012,0.04146478],"study_design_scores_gemma":[0.000283413,0.000001747109,0.000004065105,0.00001395399,0.000005927805,0.00001343122,0.0001152429,0.000002226325,0.9412673,0.003431439,0.05476593,0.0000953214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.03803218,0.00001747161,0.00001863584,0.0001815523,0.00004667833,0.00001763105,0.000004349127,0.000175225,0.9615062],"genre_scores_gemma":[0.9818878,0.000009076886,0.0003265746,0.0001404089,0.0001352555,0.00002423534,0.00004723297,0.0000139616,0.01741542],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9440908,"threshold_uncertainty_score":0.9990575,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0119406133637449,"score_gpt":0.237471284187436,"score_spread":0.2255306708236911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}