{"id":"W4244155963","doi":"10.1002/chin.200503250","title":"Carbocations","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Medicinal chemistry; Computational chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001840171,0.0005753006,0.0003099242,0.0005082691,0.0008235878,0.0008445141,0.001069867,0.0006215587,0.04542857],"category_scores_gemma":[0.000505197,0.000170129,0.0003668848,0.0002871313,0.0005664906,0.001106922,0.001012355,0.001081189,0.00559001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000974113,"about_ca_system_score_gemma":0.0003864827,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001238812,"about_ca_topic_score_gemma":0.0008970611,"domain_scores_codex":[0.9997391,0.0000204529,0.000009687283,0.0000906467,0.00005829579,0.00008181894],"domain_scores_gemma":[0.9998474,0.00002649569,0.00002348637,0.00004358239,0.00002370051,0.00003533666],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00147979,0.0003315021,0.001605974,0.002540432,0.0001623189,0.003319319,0.0008062053,0.004401471,0.404841,0.4302123,0.07237703,0.07792273],"study_design_scores_gemma":[0.0003958388,0.001144646,0.001736716,0.0002001721,0.0001568487,0.003916805,0.0004719708,0.005112554,0.4585696,0.06129189,0.4668311,0.0001718012],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3353616,0.01475416,0.04450728,0.004309473,0.004410308,0.0005779226,0.002755848,0.002242489,0.591081],"genre_scores_gemma":[0.9404072,0.003028218,0.002525852,0.0005345286,0.0001466462,0.00008988912,0.001271381,0.0001680952,0.05182817],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.04542857,"threshold_uncertainty_score":0.1519737,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0119406133637449,"score_gpt":0.237471284187436,"score_spread":0.2255306708236911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}