{"id":"W4244297390","doi":"10.1002/anie.201203362","title":"H<sub>2</sub> Activation and Hydride Transfer to Olefins by Al(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>‐Based Frustrated Lewis Pairs","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Frustrated Lewis pair; Hydride; Lewis acids and bases; Chemistry; Computer science; Organic chemistry; Catalysis; Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001053221,0.0002129785,0.000137939,0.000105505,0.0002150745,0.0003896811,0.0003497959,0.0002866059,0.003140569],"category_scores_gemma":[0.0001376437,0.000142799,0.0001510625,0.0001026918,0.0002473376,0.0004372123,0.0004371035,0.0002561392,0.0004977166],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003820251,"about_ca_system_score_gemma":0.0001571661,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007229108,"about_ca_topic_score_gemma":0.00116301,"domain_scores_codex":[0.9999206,0.000008346457,0.000003362954,0.00001342868,0.0000170738,0.00003718024],"domain_scores_gemma":[0.9999679,0.000007448608,0.000007700598,0.000006489979,0.00000381309,0.000006575881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003067373,0.00003512853,0.0004119587,0.0001877543,0.00001950286,0.0002381693,0.0001339727,0.0007294304,0.9844257,0.003715957,0.0007291081,0.009066643],"study_design_scores_gemma":[0.00002216951,0.0000813819,0.0003927933,0.000003011037,0.000004909403,0.0001278842,0.0000406611,0.001544804,0.9945261,0.000341886,0.002906932,0.000007547098],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.980735,0.0006746933,0.005708393,0.0001624788,0.00004963651,0.00003602018,0.0001241935,0.00021343,0.01229621],"genre_scores_gemma":[0.996272,0.0001455344,0.000875521,0.00003079702,0.000005724908,0.000009242588,0.00005955641,0.00001463484,0.002587007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003140569,"threshold_uncertainty_score":0.01050627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01088334406198175,"score_gpt":0.2256656772991595,"score_spread":0.2147823332371777,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}