{"id":"W4244763606","doi":"10.5194/amt-2018-113","title":"Quantification of peroxynitric acid and peroxyacyl nitrates using an ethane-based thermal dissociation peroxy radical chemical amplification cavity ring-down spectrometer","year":2018,"lang":"en","type":"preprint","venue":"","topic":"Odor and Emission Control Technologies","field":"Chemical Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Radical; Dissociation (chemistry); Mass spectrometry; Analytical Chemistry (journal); Chemical ionization; Photochemistry; Ozone; Methyl iodide; NOx; Nitric acid; Ionization; Inorganic chemistry; Physical chemistry; Environmental chemistry; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006334544,0.0005672248,0.0002812495,0.0002970457,0.000202705,0.0002308751,0.0006040772,0.0005451472,0.0008293782],"category_scores_gemma":[0.0004865772,0.000190577,0.0002921264,0.0001673865,0.0002358545,0.0003045517,0.0003931102,0.0004468788,0.0003124293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000313363,"about_ca_system_score_gemma":0.0004006922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005572833,"about_ca_topic_score_gemma":0.001026505,"domain_scores_codex":[0.9994997,0.00007955264,0.00001700189,0.0001968708,0.0001755899,0.00003118127],"domain_scores_gemma":[0.9997258,0.00006739626,0.00006307247,0.00002815663,0.0000853115,0.00003029461],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000363394,0.0000118327,0.0002866291,0.00002938485,0.000006866262,0.000009904177,0.000007572029,0.00007255951,0.9976687,0.00004283535,0.00003350757,0.001793819],"study_design_scores_gemma":[0.00001355069,0.0002395613,0.002159007,0.000006409782,0.00001418176,0.0001244724,0.00001317004,0.005391307,0.9906591,0.0000296063,0.001334118,0.00001550646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9063913,0.001648587,0.08758589,0.0001174332,0.0001104353,0.0002287581,0.0008053867,0.0006944569,0.002417684],"genre_scores_gemma":[0.8223987,0.0009770999,0.1707529,0.0001699392,0.00003708778,0.0002975052,0.0008359348,0.00006826758,0.004462572],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008293782,"threshold_uncertainty_score":0.003350019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0447533161062733,"score_gpt":0.2889772980958727,"score_spread":0.2442239819895994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}