{"id":"W4244964631","doi":"10.1002/ange.201800144","title":"Heteroleptic Copper(I)‐Based Complexes for Photocatalysis: Combinatorial Assembly, Discovery, and Optimization","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Copper; Modularity (biology); Photocatalysis; Catalysis; Chemistry; Combinatorial chemistry; BINAP; Enantioselective synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000217617,0.0002299456,0.0002901283,0.00006312002,0.0002115135,0.0001612797,0.0001601182,0.0001502157,0.0005416419],"category_scores_gemma":[0.0002856746,0.0002352037,0.0001146103,0.0001739961,0.0002708195,0.0002388009,0.000069012,0.0000796912,0.000009157056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009883906,"about_ca_system_score_gemma":0.00007709341,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002508106,"about_ca_topic_score_gemma":0.000009517289,"domain_scores_codex":[0.998709,0.00001450024,0.0003117032,0.0004504438,0.0002514095,0.0002629685],"domain_scores_gemma":[0.9988067,0.0003073672,0.0001578994,0.000382847,0.0002360364,0.0001091995],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004478502,0.0002011241,0.0008477055,0.0003586508,0.0001659216,0.000001506973,0.0001494039,0.0009112927,0.9847026,0.000716517,0.01128476,0.0002126974],"study_design_scores_gemma":[0.002298977,0.00006153013,0.00001772953,0.00005067319,0.000150619,0.000006217529,0.00005981152,0.01239702,0.9739331,0.000405315,0.01034268,0.0002763217],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.317883,0.0004873678,0.6586022,0.001037109,0.001882881,0.001125657,0.000809139,0.0006345878,0.01753804],"genre_scores_gemma":[0.9807638,0.00001643386,0.01387918,0.0003936933,0.001196164,0.0002100704,0.002004284,0.00007286548,0.001463525],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6628808,"threshold_uncertainty_score":0.9591329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02749309343999723,"score_gpt":0.2919925485763936,"score_spread":0.2644994551363964,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}