{"id":"W4245062657","doi":"10.1002/chin.201146251","title":"ChemInform Abstract: Carbocations","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Computational chemistry; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00007105074,0.0002272546,0.0001808155,0.00004249719,0.00007477643,0.00002607703,0.0003720442,0.0002443582,0.04522988],"category_scores_gemma":[0.0001575097,0.0002283269,0.0001360436,0.0001425918,0.0000747324,0.0002889373,0.0000916611,0.0003100678,0.0008032896],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001907536,"about_ca_system_score_gemma":0.00008268838,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000611039,"about_ca_topic_score_gemma":0.000004095664,"domain_scores_codex":[0.9987615,5.62941e-9,0.0003899764,0.0002324695,0.0002295992,0.0003864588],"domain_scores_gemma":[0.9988649,0.00004635978,0.0001634088,0.000569504,0.0001015925,0.000254185],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003808079,0.0001729131,0.00004088024,0.0002025068,0.00006073259,0.000006901618,0.001967443,1.412232e-8,0.4051739,0.003588186,0.02031949,0.5684289],"study_design_scores_gemma":[0.0002529378,0.000004150174,0.00008580919,0.00002487783,0.00001890406,0.00002304709,0.0004459922,0.000003201434,0.8923467,0.0007618352,0.1057809,0.0002516175],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.01083926,0.00002501236,5.252398e-7,0.00002421017,0.00009767373,0.00004804522,0.00001474836,0.0003072345,0.9886433],"genre_scores_gemma":[0.8798835,0.00002511887,0.0001775751,0.000142557,0.0001939771,0.00007503822,0.0001157676,0.00003915115,0.1193473],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.869296,"threshold_uncertainty_score":0.9999747,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03053971671326366,"score_gpt":0.2421455631158009,"score_spread":0.2116058464025372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}