{"id":"W4245225536","doi":"10.1002/ange.201810222","title":"Synthesis of the <i>Campylobacter jejuni</i> 81<b>‐</b>176 Strain Capsular Polysaccharide Repeating Unit Reveals the Absolute Configuration of its <i>O</i>‐Methyl Phosphoramidate Motif","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre","keywords":"Campylobacter jejuni; Phosphoramidate; Stereochemistry; Stereocenter; Chemistry; Absolute configuration; Biology; Biochemistry; Bacteria; Genetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001107493,0.0003637414,0.0001208718,0.0002150815,0.0001518343,0.0001523241,0.0002167479,0.0002027726,0.00203143],"category_scores_gemma":[0.0001903442,0.00008186911,0.0001514979,0.0002511492,0.0001536967,0.0001863414,0.0002001243,0.0003376458,0.0006791503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000217067,"about_ca_system_score_gemma":0.000526837,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007930714,"about_ca_topic_score_gemma":0.001038464,"domain_scores_codex":[0.9999129,0.00001059629,0.00000519848,0.00001755488,0.00002189003,0.00003182849],"domain_scores_gemma":[0.9999264,0.000009402432,0.00001902278,0.00001353119,0.00001367619,0.00001784966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000734978,0.00003699489,0.0001459106,0.00009589522,0.000005038326,0.0002029848,0.00003386887,0.0004760585,0.9887798,0.0006576806,0.0001728438,0.009319328],"study_design_scores_gemma":[0.00001254559,0.0004807612,0.001140002,0.00001032571,0.00001051341,0.0002754206,0.00002775073,0.0005109674,0.9899036,0.000237341,0.007376092,0.00001477533],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9550508,0.0008501394,0.01933528,0.0002001968,0.00009543759,0.0001747374,0.00115576,0.0002023705,0.02293543],"genre_scores_gemma":[0.9787431,0.000867917,0.01517273,0.00007339666,0.00001069142,0.00003735081,0.001179947,0.0000587595,0.003855857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00203143,"threshold_uncertainty_score":0.006795764,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01953825203669637,"score_gpt":0.2372057493294213,"score_spread":0.217667497292725,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}