{"id":"W4245225536","doi":"10.1002/ange.201810222","title":"Synthesis of the <i>Campylobacter jejuni</i> 81<b>‐</b>176 Strain Capsular Polysaccharide Repeating Unit Reveals the Absolute Configuration of its <i>O</i>‐Methyl Phosphoramidate Motif","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre","keywords":"Campylobacter jejuni; Phosphoramidate; Stereochemistry; Stereocenter; Chemistry; Absolute configuration; Biology; Biochemistry; Bacteria; Genetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007378524,0.0003927007,0.0005546605,0.00003432914,0.0002833329,0.00005964894,0.0009392093,0.0003065006,0.00179749],"category_scores_gemma":[0.001160554,0.000272156,0.0003683768,0.0004570107,0.000680287,0.0001647449,0.0001980429,0.0003549575,0.00001669392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006516447,"about_ca_system_score_gemma":0.0001227767,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001012898,"about_ca_topic_score_gemma":0.00001771466,"domain_scores_codex":[0.9975405,0.00008085521,0.0008842664,0.0004918011,0.0005301129,0.0004724378],"domain_scores_gemma":[0.9966872,0.0004810816,0.0008649198,0.001420743,0.0004356145,0.0001103863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005812621,0.00007454593,0.0002871833,0.000335465,0.0001717113,0.000003261994,0.0006537363,0.000003415386,0.9967766,0.00009401612,0.0007870704,0.0007548151],"study_design_scores_gemma":[0.0002546253,0.00001368874,0.0002239606,0.0004733384,0.0002284549,0.00001346214,0.0007337033,0.00002805985,0.9948693,0.0001754156,0.00269786,0.000288154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9607694,0.0004922525,0.00001127778,0.0006096128,0.0001457786,0.00017608,0.0005664033,0.00006125538,0.03716801],"genre_scores_gemma":[0.9956889,0.0001794479,0.00006314566,0.0001954863,0.0003330329,0.00004125861,0.00002890529,0.00005600026,0.003413882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03491951,"threshold_uncertainty_score":0.9999731,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01953825203669637,"score_gpt":0.2372057493294213,"score_spread":0.217667497292725,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}