{"id":"W4245385687","doi":"10.26434/chemrxiv.14058269","title":"Total Synthesis, Isolation, Surfactant Properties, and Biological Evaluation of Ananatosides and Related Macrodilactone-Containing Rhamnolipids","year":2021,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Microbial bioremediation and biosurfactants","field":"Environmental Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Chicoutimi; Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Fonds de Recherche du Québec - Santé; Université de Sherbrooke; Natural Sciences and Engineering Research Council of Canada; Liverpool John Moores University; Centre National de la Recherche Scientifique; Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation","keywords":"Stereochemistry; Glycosylation; Anomer; Chemistry; Rhamnose; Moiety; Chemical structure; Total synthesis; Biochemistry; Polysaccharide; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001486109,0.0005950295,0.0001922546,0.0003154014,0.0001868011,0.0002415483,0.000152445,0.0002024322,0.0004487908],"category_scores_gemma":[0.0001494376,0.00008615456,0.0002817758,0.0003492544,0.0001387345,0.0002952903,0.0002266085,0.000323508,0.0002771824],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002156128,"about_ca_system_score_gemma":0.0003316819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007980251,"about_ca_topic_score_gemma":0.001195,"domain_scores_codex":[0.9998976,0.00001744392,0.00001393227,0.00002192712,0.00003084832,0.00001817404],"domain_scores_gemma":[0.9999104,0.00001249345,0.00002694971,0.000008743836,0.00002148457,0.00001997099],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002612183,0.00001445324,0.00006327295,0.00003692622,0.000004417528,0.00003232239,0.00001550122,0.0001228786,0.9978101,0.00005452779,0.000008972995,0.001810516],"study_design_scores_gemma":[0.000002963053,0.0001507594,0.0004097554,0.000004473969,0.00001194139,0.00004124179,0.00001358394,0.0002095684,0.9979407,0.00001759542,0.001192598,0.000004881987],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844208,0.003593641,0.008348998,0.00006165125,0.00002937187,0.00009240731,0.0007650311,0.00005921066,0.002628889],"genre_scores_gemma":[0.9801728,0.004040258,0.01215541,0.00005216755,0.00001435377,0.00007396918,0.001038721,0.00002957761,0.00242281],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007980251,"threshold_uncertainty_score":0.001586795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04789418311537623,"score_gpt":0.2416129653447806,"score_spread":0.1937187822294043,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}