{"id":"W4245436627","doi":"10.26434/chemrxiv.7479665","title":"Ligand-Centered Electrochemical Processes Enable CO2 Reduction with a Nickel Bis(triazapentadienyl) Complex","year":2018,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Ligand (biochemistry); Electrochemistry; Reactivity (psychology); Redox; Electron paramagnetic resonance; Metal; Crystallography; Stereochemistry; Medicinal chemistry; Inorganic chemistry; Physical chemistry; Electrode; Physics; Nuclear magnetic resonance; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000101755,0.0002703954,0.0002132736,0.00007620277,0.0002113408,0.0004002486,0.0006432207,0.0004100646,0.00268897],"category_scores_gemma":[0.0001985748,0.0001554917,0.0001098661,0.0001398687,0.0001965815,0.000317316,0.0003541221,0.0007856274,0.00109428],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00046286,"about_ca_system_score_gemma":0.0002222408,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001011465,"about_ca_topic_score_gemma":0.001896613,"domain_scores_codex":[0.9998378,0.0000136545,0.00001064163,0.00005558548,0.0000455214,0.00003682956],"domain_scores_gemma":[0.9999433,0.000009075004,0.00001131863,0.00001004905,0.00001529971,0.00001109237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009336462,0.00004608803,0.00007817782,0.0001363713,0.000009940313,0.0001266439,0.0001052784,0.0003105285,0.9934313,0.001184099,0.0004870299,0.003991215],"study_design_scores_gemma":[0.00001281891,0.00008709643,0.0001420751,0.000002451683,0.000004694717,0.00008637752,0.00002284781,0.0009973283,0.9927081,0.00008795962,0.005840896,0.000007310159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9476737,0.001551625,0.02988988,0.0008834557,0.0001932771,0.000119962,0.0005525838,0.0009869384,0.01814857],"genre_scores_gemma":[0.9862743,0.0004531851,0.007265273,0.00009997488,0.0000132579,0.00004779737,0.0003055896,0.00006985212,0.005470798],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00268897,"threshold_uncertainty_score":0.008995533,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02799170949485549,"score_gpt":0.2626973617928416,"score_spread":0.2347056522979861,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}