{"id":"W4245786812","doi":"10.26434/chemrxiv.11864934","title":"Expanding the Family of Tetrahalide Iron Complexes: Synthesis, Structure and Biological Applications.","year":2020,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Council of Scientific and Industrial Research, India; Trent University; Bangladesh Council of Scientific and Industrial Research; Nottingham Trent University","keywords":"Protonation; Chemistry; Octahedron; Bromide; Oxidation state; Coordination sphere; Redox; Bacteria; Biofilm; Nitrogen; Crystallography; Stereochemistry; Metal; Inorganic chemistry; Ion; Organic chemistry; Crystal structure; Biology","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001931688,0.0002993163,0.0001901704,0.0002089849,0.0001725375,0.0003742176,0.0004175852,0.0004525684,0.002001763],"category_scores_gemma":[0.0002150771,0.000135562,0.0001274228,0.0002071941,0.0002323053,0.0003823936,0.0004045823,0.0004914716,0.0008701286],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003248862,"about_ca_system_score_gemma":0.0002498914,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003544497,"about_ca_topic_score_gemma":0.0005716079,"domain_scores_codex":[0.9998941,0.00001605518,0.000006809453,0.00002758152,0.00003923715,0.00001622039],"domain_scores_gemma":[0.9999357,0.00001069108,0.00001348307,0.000009737098,0.00001347661,0.00001687203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001421758,0.00003874713,0.0002604364,0.000337891,0.0000123578,0.000112383,0.00007933324,0.0002888536,0.9597768,0.002500674,0.00121855,0.03523178],"study_design_scores_gemma":[0.00005006266,0.0005874126,0.001284114,0.00005208117,0.00002871257,0.00195928,0.00005240822,0.001100841,0.8453561,0.00157677,0.1479317,0.00002055375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7767867,0.07424359,0.09870424,0.002808362,0.0005301346,0.0003805469,0.001225838,0.001150707,0.04416984],"genre_scores_gemma":[0.8921911,0.02587581,0.05964762,0.0007806229,0.00009202978,0.000163065,0.001323256,0.0002112145,0.01971524],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002001763,"threshold_uncertainty_score":0.006696582,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04193034503113257,"score_gpt":0.2698128419987713,"score_spread":0.2278824969676387,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}