{"id":"W4246477594","doi":"10.1002/ange.201914015","title":"N‐Heterocyclic Carbene Stabilized Dicarbondiphosphides: Strong Neutral Four‐Membered Heterocyclic 6π‐Electron Donors","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"ETH Zürich Foundation; National Natural Science Foundation of China; Fundamental Research Funds for the Central Universities; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Carbene; Chemistry; Ring (chemistry); Conjugated system; Crystallography; Aromaticity; Spectroscopy; Stereochemistry; Infrared spectroscopy; Medicinal chemistry; Molecule; Catalysis; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006110568,0.0001694555,0.0001185512,0.00008955679,0.00009861065,0.0001873367,0.0002097464,0.0001446244,0.002104915],"category_scores_gemma":[0.00007517075,0.00007437735,0.00004126568,0.00006639297,0.0001309852,0.0001624655,0.0002621563,0.0002078248,0.0002835923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002216392,"about_ca_system_score_gemma":0.000090521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002921896,"about_ca_topic_score_gemma":0.0005480849,"domain_scores_codex":[0.9999516,0.000006195504,0.000002687551,0.00001128275,0.0000159967,0.00001214964],"domain_scores_gemma":[0.9999685,0.000005127785,0.000005915354,0.000004625778,0.000005135287,0.00001067089],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001858176,0.00003515448,0.0001728301,0.0002022681,0.00001419037,0.0001202116,0.00002710255,0.0004937514,0.9884344,0.002995007,0.000651654,0.006667635],"study_design_scores_gemma":[0.00004704014,0.0003334766,0.001030034,0.00000934184,0.000009675423,0.000140556,0.00001505742,0.001489301,0.9863457,0.0002869929,0.01028328,0.000009542686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9794729,0.001624149,0.002617305,0.0001008158,0.00005940457,0.00003858505,0.0002298062,0.00006969016,0.01578717],"genre_scores_gemma":[0.9966774,0.0004042757,0.001202467,0.00003055397,0.000005232254,0.00001457698,0.00008359043,0.000006432206,0.001575441],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002104915,"threshold_uncertainty_score":0.007041633,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02426594472446099,"score_gpt":0.2389633894015523,"score_spread":0.2146974446770913,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}