{"id":"W4247192244","doi":"10.32920/ryerson.14663577.v1","title":"Hypercoordinated Organotin(IV) Compounds Containing ĸ²-C,O- And ĸ²,N- Chelating Ligands: Synthesis, Characterization, and Polymerization Behaviour","year":2021,"lang":"en","type":"preprint","venue":"","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University; Sciencetech (Canada)","funders":"","keywords":"Polymerization; Chemistry; Ether; Trigonal bipyramidal molecular geometry; Transmetalation; Polymer chemistry; Silsesquioxane; Tetrahedral molecular geometry; Chelation; Oligomer; Ligand (biochemistry); Polymer; Amine gas treating; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000124986,0.0002520569,0.0001189705,0.000150651,0.00008261438,0.0002397584,0.0001493597,0.0001693907,0.000701144],"category_scores_gemma":[0.0001154876,0.00009874822,0.00005934562,0.0002072026,0.0001392377,0.0001315418,0.00008864444,0.0001799283,0.0003353409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002417349,"about_ca_system_score_gemma":0.0001794843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004442034,"about_ca_topic_score_gemma":0.0007099833,"domain_scores_codex":[0.9999217,0.00001354062,0.000007755878,0.0000178858,0.00001900066,0.00002013468],"domain_scores_gemma":[0.9999201,0.0000107058,0.00002422138,0.000008403391,0.00001501929,0.00002150522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003588838,0.000006725963,0.0000849237,0.0000226794,0.000002114911,0.00001676098,0.00001070153,0.00009781325,0.9986506,0.00006236391,0.00001703777,0.0009924446],"study_design_scores_gemma":[0.000003764193,0.00007191053,0.0004930642,0.00000150824,0.000004113463,0.00004081606,0.000007923767,0.0001762078,0.9984085,0.00001347518,0.0007763875,0.00000234629],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941866,0.0007413777,0.00283914,0.00002213011,0.000005802797,0.00002395505,0.0002555673,0.00007253798,0.001852841],"genre_scores_gemma":[0.993105,0.0005027138,0.004027942,0.00001512695,0.000002938484,0.00002131316,0.0003220515,0.00002445285,0.001978399],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000701144,"threshold_uncertainty_score":0.002345502,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01208701678127503,"score_gpt":0.2139541172578903,"score_spread":0.2018671004766153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}