{"id":"W4247379648","doi":"10.1055/s-2005-871949","title":"Diastereoselective Synthesis of 1,2,3-Substituted Potassium Cyclopropyl Trifluoroborates via an Unusual Zinc-Boron Exchange","year":2005,"lang":"en","type":"article","venue":"Synlett","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Boron; Zinc; Potassium; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005802262,0.0004032133,0.0005184834,0.0001300079,0.0001790944,0.00001782579,0.0005367309,0.0005623719,0.003658928],"category_scores_gemma":[0.0002859637,0.0004072719,0.0001233528,0.000451965,0.0003576291,0.0003035703,0.0001297587,0.0007946019,0.0002674172],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002332016,"about_ca_system_score_gemma":0.0001557376,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007006763,"about_ca_topic_score_gemma":0.00007136887,"domain_scores_codex":[0.9975785,0.0003945706,0.0005744613,0.0005528255,0.0002565891,0.0006430322],"domain_scores_gemma":[0.9981633,0.0005682447,0.0002878638,0.0004629837,0.0002032273,0.0003143552],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004815509,0.00099399,0.003033615,0.0001777091,0.0003326148,0.00004696444,0.0009278345,0.0001789299,0.8760654,0.0001264205,0.004476367,0.1131585],"study_design_scores_gemma":[0.00101576,0.0001160919,0.00182074,0.00002325598,0.000245552,0.00005897193,0.0001142468,0.001302303,0.965697,0.00007260815,0.02910682,0.0004266426],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988695,0.0009265432,0.0002820897,0.001715771,0.0007870907,0.0004642493,0.0001996639,0.0002755121,0.006654052],"genre_scores_gemma":[0.9960873,0.0001261681,0.001183112,0.0004702846,0.001153792,0.00009830661,0.00005346992,0.00007161198,0.0007560197],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1127319,"threshold_uncertainty_score":0.9998379,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05500578098576805,"score_gpt":0.3844881924977875,"score_spread":0.3294824115120195,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}