{"id":"W4247442686","doi":"10.1063/1.3194797","title":"Formation mechanisms of oxygen atoms in the O(PJ3) state from the 157nm photoirradiation of amorphous water ice at 90K","year":2009,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; Queen's University","keywords":"Radical; Photodissociation; Photochemistry; Chemistry; Amorphous solid; Exothermic reaction; Oxygen; Desorption; Ionization; Resonance-enhanced multiphoton ionization; Amorphous ice; Ground state; Photoionization; Physical chemistry; Adsorption; Atomic physics; Crystallography; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004845276,0.00007619678,0.0001583814,0.000003484422,0.00004347569,0.00001086571,0.0003436331,0.0000276759,0.00009601312],"category_scores_gemma":[0.00001025785,0.00002989379,0.00007111103,0.0001101676,0.00005079879,0.0001965119,0.000009543889,0.0001569944,0.00001266715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007851369,"about_ca_system_score_gemma":0.00001289042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000295499,"about_ca_topic_score_gemma":0.00002873487,"domain_scores_codex":[0.9990394,0.00009631612,0.000350772,0.00004185719,0.0003404978,0.00013119],"domain_scores_gemma":[0.9992551,0.0002076788,0.0003312307,0.0001366837,0.00004602579,0.00002332103],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001015962,0.0001802429,0.00222019,0.00002567335,0.00008624842,0.000006122007,0.02750934,0.01156175,0.9264332,0.0001730862,0.001694711,0.0290935],"study_design_scores_gemma":[0.0005787115,0.0002597574,0.02059305,0.00003804853,0.00008759809,0.00002022776,0.000969636,0.007661133,0.8375051,0.1320192,0.0001637332,0.0001038026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979525,0.0001136468,0.0007646366,0.0007668052,0.00003993152,0.00008043812,0.00002049189,0.000002087137,0.0002594934],"genre_scores_gemma":[0.9991367,0.00008834361,0.0001479448,0.0005241688,0.00007623826,1.136378e-7,0.00001909951,0.000001847121,0.000005468757],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1318461,"threshold_uncertainty_score":0.1219034,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009262883890895988,"score_gpt":0.1916093105437125,"score_spread":0.1823464266528165,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}