{"id":"W4247470931","doi":"10.1002/ange.201710241","title":"A Nickel‐Catalyzed Carbonyl‐Heck Reaction","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Heck reaction; Catalysis; Aldehyde; Olefin fiber; Reactivity (psychology); Ligand (biochemistry); Combinatorial chemistry; Coupling reaction; Nickel; Ketone; Amine gas treating; Organic synthesis; Intermolecular force; Molecule; Organic chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002114105,0.0005338559,0.0002006851,0.0003258894,0.0005433384,0.0003295232,0.0006310182,0.000322474,0.006251835],"category_scores_gemma":[0.0001621339,0.0001854116,0.0002716431,0.0002527302,0.0002257435,0.0005226623,0.0005745852,0.0006324551,0.002170503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005661125,"about_ca_system_score_gemma":0.0005953046,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007744273,"about_ca_topic_score_gemma":0.00154424,"domain_scores_codex":[0.9997607,0.00002038204,0.00002052498,0.00005358681,0.00007058358,0.00007424284],"domain_scores_gemma":[0.9999434,0.000006184061,0.00000822823,0.00001330137,0.00001303261,0.00001592971],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000239393,0.0004911178,0.001064975,0.001113571,0.0001201233,0.001898444,0.0003839769,0.001157896,0.9059668,0.02177179,0.00802581,0.05776606],"study_design_scores_gemma":[0.00003268465,0.0003696205,0.0008555002,0.00002524404,0.00004924486,0.0009627275,0.00005543395,0.001055575,0.9550347,0.0005200161,0.0410141,0.00002510686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7191647,0.00510318,0.05671932,0.001159232,0.001125587,0.0005554282,0.001532421,0.001562131,0.2130781],"genre_scores_gemma":[0.9743722,0.00166721,0.007513081,0.0000943984,0.00005552652,0.00006756561,0.0004192659,0.00003537871,0.01577537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006251835,"threshold_uncertainty_score":0.02091449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02595706872644258,"score_gpt":0.2892343830786556,"score_spread":0.263277314352213,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}