{"id":"W4247615205","doi":"10.1002/ange.201403693","title":"The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh<sub>2</sub>][B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>]<sub>2</sub>","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Phosphonium; Chemistry; Lewis acids and bases; Salt (chemistry); Phosphonium salt; Hydrosilylation; Stoichiometry; Catalysis; Inorganic chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001387521,0.0003671423,0.0002713897,0.0001306149,0.0001723941,0.0002411553,0.0003630415,0.0003197366,0.002116264],"category_scores_gemma":[0.0001878074,0.0001589777,0.00008780776,0.0001537222,0.0002784912,0.000335786,0.0003207034,0.0003119558,0.000716014],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002332019,"about_ca_system_score_gemma":0.0002265004,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006170633,"about_ca_topic_score_gemma":0.0008325514,"domain_scores_codex":[0.9999037,0.00001004345,0.000009854379,0.00002384725,0.0000318575,0.00002067988],"domain_scores_gemma":[0.9999279,0.000005350208,0.00001792594,0.000009819596,0.00001942542,0.00001963593],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008358146,0.000005473541,0.00008492465,0.00006992456,0.000005104715,0.00005685379,0.00001413474,0.00007003776,0.9976803,0.0001829198,0.0001127932,0.001633873],"study_design_scores_gemma":[0.0000183371,0.00009722768,0.0002767858,0.00000213754,0.000006947969,0.0001404146,0.000005965894,0.0001593676,0.9967436,0.00002329678,0.002522523,0.000003478714],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.980616,0.00105319,0.007098485,0.0002091085,0.0001141174,0.00007864005,0.0004514501,0.0002421037,0.01013697],"genre_scores_gemma":[0.9902355,0.0004038251,0.005005483,0.00006786286,0.00001897982,0.0000190601,0.0002889447,0.00004049456,0.00391985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002116264,"threshold_uncertainty_score":0.007079601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00723957413707558,"score_gpt":0.2061125162966465,"score_spread":0.1988729421595709,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}