{"id":"W4247615205","doi":"10.1002/ange.201403693","title":"The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh<sub>2</sub>][B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>]<sub>2</sub>","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Phosphonium; Chemistry; Lewis acids and bases; Salt (chemistry); Phosphonium salt; Hydrosilylation; Stoichiometry; Catalysis; Inorganic chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001929512,0.003999876,0.003182212,0.0004688523,0.002629033,0.001379422,0.004471318,0.003652819,0.0003003629],"category_scores_gemma":[0.001621921,0.003971552,0.002089481,0.002506083,0.002498776,0.001380009,0.001913853,0.00452341,0.003709112],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002414685,"about_ca_system_score_gemma":0.00194509,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007909922,"about_ca_topic_score_gemma":0.0004162729,"domain_scores_codex":[0.9820793,0.0003753766,0.003809659,0.005019257,0.003464349,0.005252032],"domain_scores_gemma":[0.9852082,0.001685969,0.002624904,0.00657324,0.001210376,0.002697345],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004609808,0.0009974126,0.00121289,0.001259244,0.0009475777,0.0001507165,0.0008017531,0.00001775882,0.9257858,0.0001197515,0.04448478,0.02376127],"study_design_scores_gemma":[0.005619733,0.0002122395,0.001031492,0.0007843283,0.001176409,0.000275239,0.0006440734,0.00009281032,0.9671233,0.0005914277,0.0179887,0.004460268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765769,0.007687151,0.0001167482,0.004435873,0.001994116,0.001264571,0.0007883729,0.002271954,0.004864267],"genre_scores_gemma":[0.9748394,0.01327073,0.00006546979,0.002702742,0.004538582,0.0008343862,0.00212083,0.001291547,0.0003362838],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04133741,"threshold_uncertainty_score":0.9996572,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00723957413707558,"score_gpt":0.2061125162966465,"score_spread":0.1988729421595709,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}