{"id":"W4248255427","doi":"10.1002/ange.201904817","title":"Halogen Bonding Helicates Encompassing Iodonium Cations","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Nemzeti Kutatási Fejlesztési és Innovációs Hivatal; Svenska Forskningsrådet Formas","keywords":"Chemistry; Halogen; van der Waals force; Ion; Crystallography; Halogen bond; Nuclear magnetic resonance spectroscopy; Solid-state; Aryl; Van der Waals radius; Helix (gastropod); Molecule; Spectroscopy; Stereochemistry; Computational chemistry; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001268935,0.0002613004,0.0001659794,0.00008951384,0.0001957984,0.0002428385,0.0001557695,0.0001873387,0.0009438664],"category_scores_gemma":[0.0001640867,0.0001474613,0.00009949938,0.000101654,0.0001549174,0.00016148,0.0001727369,0.0002390802,0.0004715484],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002922422,"about_ca_system_score_gemma":0.0001933003,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003220328,"about_ca_topic_score_gemma":0.0005468832,"domain_scores_codex":[0.9999229,0.0000161313,0.000005852927,0.00001683627,0.00001431272,0.00002395223],"domain_scores_gemma":[0.9998884,0.00001443268,0.00003369183,0.00001518674,0.00001336191,0.00003486282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001742439,0.00002222619,0.0003504334,0.00005336705,0.00001017963,0.0002369327,0.00007435451,0.001486027,0.9922861,0.001643398,0.0001975059,0.003465204],"study_design_scores_gemma":[0.00003202569,0.0004439593,0.0010477,0.00001104101,0.00001804239,0.0001640157,0.00003695033,0.002385576,0.9852632,0.0002340014,0.01034718,0.00001624253],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987574,0.0004854083,0.00675649,0.00006393225,0.00006260351,0.00005491562,0.0001763261,0.0001309025,0.0046954],"genre_scores_gemma":[0.994965,0.0002366938,0.002770868,0.00004211468,0.000007763353,0.00002587061,0.0001092673,0.00002015699,0.001822151],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009438664,"threshold_uncertainty_score":0.003157556,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0132092029823314,"score_gpt":0.2463208619491253,"score_spread":0.2331116589667939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}