{"id":"W4248302235","doi":"10.1002/ange.201310232","title":"The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal‐Catalyzed Reactions of Alkylidenecyclopropanes","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Metallacycle; Allene; Cycloisomerization; Synthon; Rhodium; Chemistry; Catalysis; Ligand (biochemistry); Combinatorial chemistry; Stereochemistry; Organic chemistry; X-ray crystallography; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000209162,0.0001286567,0.0002351749,0.00007007275,0.00005843234,0.00001541525,0.0001273035,0.00009747699,0.00003831619],"category_scores_gemma":[0.0001513561,0.0001046977,0.00005427052,0.0001846797,0.00009144921,0.0001460716,0.00005752029,0.0001177493,0.000002593797],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000402475,"about_ca_system_score_gemma":0.00002051278,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001232012,"about_ca_topic_score_gemma":0.00004675465,"domain_scores_codex":[0.9990269,0.00002121511,0.0004517713,0.0002070505,0.000141767,0.0001513017],"domain_scores_gemma":[0.9990042,0.0001432251,0.0003864054,0.0003166141,0.0001072692,0.00004227458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004486572,0.00003248259,0.001472434,0.0001500058,0.00002028058,2.353121e-7,0.0003294367,7.607658e-7,0.9933709,0.0001181061,0.000001532688,0.004458941],"study_design_scores_gemma":[0.0004888168,0.00001281916,0.00898852,0.00006761798,0.00003234119,0.000007469282,0.0002594143,0.0001213046,0.9884685,0.0002668365,0.00118723,0.00009909216],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978639,0.00008688503,0.0001516949,0.00008556582,0.00004587368,0.0001002072,0.00001560116,0.00003565728,0.001614552],"genre_scores_gemma":[0.9991984,0.0002978832,0.00007536491,0.000006352906,0.00003963945,0.00003931672,0.000146628,0.00002041626,0.000175983],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007516087,"threshold_uncertainty_score":0.4269449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01034317178285559,"score_gpt":0.2319676984063646,"score_spread":0.221624526623509,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}