{"id":"W4248903995","doi":"10.1002/ange.201705903","title":"Photochemical Dual‐Catalytic Synthesis of Alkynyl Sulfides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Carbazole; Sulfide; Photocatalysis; Combinatorial chemistry; Photochemistry; Steric effects; Functional group; Organic synthesis; Sulfur; Continuous flow; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002699491,0.0003239687,0.0005430604,0.00006294854,0.0002028355,0.00008499274,0.0009506567,0.0003127515,0.001476569],"category_scores_gemma":[0.002299205,0.0003143703,0.0002836316,0.00005436124,0.0004903188,0.0002094311,0.0002726601,0.0002314203,0.00006054728],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009925565,"about_ca_system_score_gemma":0.00007930343,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001780395,"about_ca_topic_score_gemma":0.000008565288,"domain_scores_codex":[0.9982432,0.000009294159,0.0004465681,0.0004930734,0.0003873365,0.0004205858],"domain_scores_gemma":[0.9967292,0.0005425961,0.0004470632,0.001999776,0.0001230844,0.0001582881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005451575,0.000127412,0.003692186,0.0002458032,0.00009080715,0.00002792581,0.00005428047,6.406206e-8,0.989611,0.00003350489,0.004159013,0.001903462],"study_design_scores_gemma":[0.0002658842,0.000008497825,0.0002160732,0.0003275597,0.0001140235,0.00001912357,0.00007258685,0.000003344103,0.993982,0.0004872511,0.00416156,0.0003420636],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.860334,0.0002047449,0.00000796554,0.0002361635,0.00003666124,0.00009089168,0.00009406816,0.0002449894,0.1387505],"genre_scores_gemma":[0.9975032,0.00008862782,0.0009733966,0.00004498694,0.0001998249,0.00009128829,0.00002402625,0.00006700151,0.001007601],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1377429,"threshold_uncertainty_score":0.9999309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02403743050073971,"score_gpt":0.2729378611969697,"score_spread":0.24890043069623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}