{"id":"W4248903995","doi":"10.1002/ange.201705903","title":"Photochemical Dual‐Catalytic Synthesis of Alkynyl Sulfides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Carbazole; Sulfide; Photocatalysis; Combinatorial chemistry; Photochemistry; Steric effects; Functional group; Organic synthesis; Sulfur; Continuous flow; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001027921,0.0003388237,0.0001938616,0.0001739256,0.0001408213,0.0001813904,0.0002157821,0.0001812141,0.00108627],"category_scores_gemma":[0.00007173223,0.0001319837,0.0001617419,0.0001531148,0.0001599243,0.0001723463,0.000223566,0.0002787269,0.0003491868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003471338,"about_ca_system_score_gemma":0.0002570314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005027638,"about_ca_topic_score_gemma":0.00145147,"domain_scores_codex":[0.9999273,0.00000580808,0.000005978281,0.00002105606,0.00002058564,0.00001927416],"domain_scores_gemma":[0.9999559,0.000005419181,0.00001069264,0.000005376639,0.000009308571,0.00001327125],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002279962,0.00001398163,0.00005106431,0.00004098732,0.000005610914,0.00007785338,0.00002102002,0.0001622033,0.9967216,0.0004434129,0.0000840275,0.002355454],"study_design_scores_gemma":[0.000006983825,0.00008946699,0.000238348,0.000001684277,0.000005609312,0.0000539549,0.000006244602,0.0004901823,0.9969873,0.00003920495,0.002078279,0.000002705441],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747601,0.001450371,0.01391888,0.0001083777,0.0001232968,0.00006853363,0.0003886998,0.0002327055,0.008949061],"genre_scores_gemma":[0.9892926,0.0007435578,0.006369606,0.00002130617,0.00001046531,0.0000246946,0.000180395,0.00003182261,0.003325499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00108627,"threshold_uncertainty_score":0.003633916,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02403743050073971,"score_gpt":0.2729378611969697,"score_spread":0.24890043069623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}