{"id":"W4248917922","doi":"10.1007/b101000","title":"Asymmetric Induction in Organic Photochemistry via the Solid-State Ionic Chiral Auxiliary Approach","year":2005,"lang":"en","type":"book-chapter","venue":"Topics in current chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Photoisomerization; Ionic bonding; Asymmetric induction; Methane; Mechanistic organic photochemistry; Photochemistry; Chiral auxiliary; Solid-state; Enantioselective synthesis; Organic chemistry; Isomerization; Ion; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004264717,0.0008951006,0.0009367472,0.0002623532,0.0001224656,0.00008616046,0.001227562,0.001094512,0.003032213],"category_scores_gemma":[0.0001732334,0.0008157713,0.0004535571,0.0005493028,0.0002153754,0.0001016446,0.0004140671,0.003136554,0.00006857118],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001239588,"about_ca_system_score_gemma":0.0003093747,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002067639,"about_ca_topic_score_gemma":0.00001111998,"domain_scores_codex":[0.9959391,0.00001729652,0.001262501,0.001227651,0.0008325917,0.000720871],"domain_scores_gemma":[0.9974374,0.0001498407,0.0006554588,0.00149811,0.0000921871,0.000166961],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008390289,0.001115042,0.0009355941,0.003628893,0.0004253162,0.00006418457,0.0003953656,0.0001568316,0.01228568,0.000340264,0.001706815,0.9788621],"study_design_scores_gemma":[0.003643827,0.00001921845,0.0003290372,0.002419077,0.0008198068,0.0003424512,0.000362079,0.002971556,0.5885211,0.01034408,0.3846948,0.005532946],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.01169548,0.01482997,0.00007184665,0.0001234884,0.0003418913,0.0003232911,0.00009934264,0.0001334937,0.9723812],"genre_scores_gemma":[0.2534445,0.009543565,0.0001935772,0.00006669536,0.00604723,0.0004054081,0.001941082,0.0004015219,0.7279565],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.9733292,"threshold_uncertainty_score":0.9994293,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02028745567004124,"score_gpt":0.251732562490242,"score_spread":0.2314451068202007,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}